Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Computational Analysis of Two-Phase Flow Dynamics in a Porous Transport Layer of a PEM Electrolyzer

Version 1 : Received: 16 November 2023 / Approved: 16 November 2023 / Online: 16 November 2023 (11:26:04 CET)

How to cite: Weng, F.; Dlamini, M.M.; Tirumalasetti, P.R.; Hung, B.–.; Nelli, D.; Chiu, P.; Hung, C.C. Computational Analysis of Two-Phase Flow Dynamics in a Porous Transport Layer of a PEM Electrolyzer. Preprints 2023, 2023111078. https://doi.org/10.20944/preprints202311.1078.v1 Weng, F.; Dlamini, M.M.; Tirumalasetti, P.R.; Hung, B.–.; Nelli, D.; Chiu, P.; Hung, C.C. Computational Analysis of Two-Phase Flow Dynamics in a Porous Transport Layer of a PEM Electrolyzer. Preprints 2023, 2023111078. https://doi.org/10.20944/preprints202311.1078.v1

Abstract

This research presents a comprehensive computational analysis of the two-phase flow dynamics within a three-dimensional porous transport layer (PTL) in a proton exchange membrane (PEM) electrolyzer. Employing advanced computational fluid dynamics (CFD) and a volume of fluid (VOF) approach, the study utilizes the finite-volume method to model a time-dependent, isothermal process within a laminar flow regime. Notably, the study treats oxygen as the dispersed phase and water as the continuous phase within the system. Investigations on the anode side uncovered the formation of gas bubbles on the electrode's surface subsequent to the electrochemical reaction. The simulation, spanning 5 seconds with 0.25-second intervals, highlights the critical role of the time interval between the initiation and 2 seconds in achieving pressure and velocity equilibrium within the PTL. The initial 0.75 seconds witnessed a peak in oxygen concentration, followed by its movement across the PTL, exhibiting a transition from regions of lower to higher concentration, consistent with known physical behaviour. Remarkably, the model recorded the highest pressure of 3.5 Pa at 0.25 s. Furthermore, the study observed an incremental pressure drop from 0.25 s to 0.5 s and 1 s, approximately amounting to 28.5% and 20%, respectively, ultimately leading to a uniform pressure distribution within the model. Over time, the pressure drop intensified across the entire model due to the evolving nature of the oxygen gas. These findings provide valuable insights into the complex dynamics of two-phase flow processes within PEM electrolyzers, contributing to the advancement of sustainable energy technologies.

Keywords

PEMWE; two-phase flow simulation; PTL; pressure distribution; oxygen generation

Subject

Engineering, Energy and Fuel Technology

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