Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Hot-Pressed Super-Elastic Graphene Aerogel with Bidirectional Thermal Conduction Properties as Thermal Interface Materials

Version 1 : Received: 3 November 2023 / Approved: 3 November 2023 / Online: 6 November 2023 (09:34:26 CET)

A peer-reviewed article of this Preprint also exists.

Lv, P.; Zhou, X.; Chen, S. Hot-Pressed Super-Elastic Graphene Aerogel with Bidirectional Thermal Conduction Properties as Thermal Interface Materials. Materials 2023, 16, 7419. Lv, P.; Zhou, X.; Chen, S. Hot-Pressed Super-Elastic Graphene Aerogel with Bidirectional Thermal Conduction Properties as Thermal Interface Materials. Materials 2023, 16, 7419.

Abstract

Traditional graphene-based films normally possess high thermal conductivity (TC) only along single direction, which is not suitable for thermal interface materials (TIMs). Here, a graphene film with excellent bidirectional TC and mechanical properties was prepared by hot-pressing super-elastic graphene aerogel (SEGA). Thermal annealing at 1800℃ improves the further restacking of graphene sheets, bring the SEGA high structure stability for enduring the hot-pressing process. The junctions and nodes between the graphene layers in the hot-pressed SEGA (HPSEGA) film provide bidirectional heat transport paths. The in-plane TC and through-plane TC of HPSEGA film with thickness of 101μm reach 740 Wm-1K-1 and 42.5 Wm-1K-1, respectively. In addition, HPSEGA film with higher thickness still maintains excellent thermal transport properties due to the interconnected structure reducing the effect of the defects. The infrared thermal images visually manifest the excellent thermal-transfer capability and thermal dissipation efficiency of the HPSEGA films, indicating the great potential as advanced bidirectional TIMs.

Keywords

thermal interface materials; graphene; hot-pressing; thermal annealing; bidirectional

Subject

Chemistry and Materials Science, Materials Science and Technology

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