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Integration of Modified Solvay Process for Sodium Bicarbonate Synthesis from Saline Brines with Steelmaking for Utilization of Electric Arc Furnace Slag in CO2 Sequestration and Reagent Regeneration
Anto, S.M.; Ali, A.; Santos, R.M. Integration of Modified Solvay Process for Sodium Bicarbonate Synthesis from Saline Brines with Steelmaking for Utilization of Electric Arc Furnace Slag in CO2 Sequestration and Reagent Regeneration. Minerals2024, 14, 97.
Anto, S.M.; Ali, A.; Santos, R.M. Integration of Modified Solvay Process for Sodium Bicarbonate Synthesis from Saline Brines with Steelmaking for Utilization of Electric Arc Furnace Slag in CO2 Sequestration and Reagent Regeneration. Minerals 2024, 14, 97.
Anto, S.M.; Ali, A.; Santos, R.M. Integration of Modified Solvay Process for Sodium Bicarbonate Synthesis from Saline Brines with Steelmaking for Utilization of Electric Arc Furnace Slag in CO2 Sequestration and Reagent Regeneration. Minerals2024, 14, 97.
Anto, S.M.; Ali, A.; Santos, R.M. Integration of Modified Solvay Process for Sodium Bicarbonate Synthesis from Saline Brines with Steelmaking for Utilization of Electric Arc Furnace Slag in CO2 Sequestration and Reagent Regeneration. Minerals 2024, 14, 97.
Abstract
In the pursuit of sustainable solutions for carbon dioxide CO2 sequestration and emission reduction in the steel industry, this study presents an innovative integration of steelmaking slag with the modified Solvay process for sodium bicarbonate (NaHCO3) synthesis from saline brines. Utilizing diverse minerals, including electric arc furnace (EAF) slag, olivine, and kimberlite, the study explored their reactivity under varied pH conditions and examined their potential in ammonium regeneration. Advanced techniques such as XRD and ICP-OES were employed to meticulously analyze mineralogical transformations and elemental concentrations. The findings demonstrate that steelmaking slag, owing to its superior reactivity and pH buffering capabilities, outperforms natural minerals. The integration of finer slag particles significantly elevated pH levels, facilitating efficient ammonium regeneration. Geochemical modeling provided valuable insights into mineral stability and reactivity which aligned with the ICP-OES results. This synergistic approach not only aids in CO2 capture through mineral carbonation but also minimizes waste, showcasing its potential as a sustainable and environmentally responsible solution for CO2 mitigation in the steel industry.
Copyright:
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