Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Effect of Artificial Saliva Modification on Corrosion Resistance and Electronic Properties of Bego Wirobond C Dental Alloy

Version 1 : Received: 18 October 2023 / Approved: 19 October 2023 / Online: 19 October 2023 (05:18:22 CEST)

A peer-reviewed article of this Preprint also exists.

Łosiewicz, B.; Osak, P.; Kubisztal, J.; Górka-Kulikowska, K. Effect of Artificial Saliva Modification on the Corrosion Resistance and Electronic Properties of Bego Wirobond® C Dental Alloys. Appl. Sci. 2023, 13, 12185. Łosiewicz, B.; Osak, P.; Kubisztal, J.; Górka-Kulikowska, K. Effect of Artificial Saliva Modification on the Corrosion Resistance and Electronic Properties of Bego Wirobond® C Dental Alloys. Appl. Sci. 2023, 13, 12185.

Abstract

Wirobond C is a commercial dental casting alloy suitable for the fabrication of crowns, bridges as well as metal-ceramic restorations. This work aims with the study of the effect of ready-to-use Listerine® and Meridol® mouthwashes and sodium fluoride on corrosion resistance of the CoCrMo dental alloy to electrochemical corrosion in artificial saliva at 37 °C. SEM, EDS, SKP, and microhardness investigations were carried out to characterize the material under study. In vitro corrosion resistance of the CoCrMo alloy was conducted by the open circuit potential method, electrochemical impedance spectroscopy, and anodic polarization curves. The presence of Co 59.8(8) wt.%, Cr 31.5(4) wt.%, and Mo 8.8(6) wt.% was confirmed. The CoCrMo alloy was characterized by Vickers microhardness of 445(31) µHV0.3. Based on EIS data, the capacitive behavior and high corrosion resistance of CoCrMo alloy was revealed. The kinetics of pitting corrosion in the artificial saliva was lower after the modification with NaF and Listerine and Meridol mouthwashes. The potentiodynamic characteristics revealed the passive behavior of CoCrMo alloy in all solutions. Based on the SKP measurements of the CoCrMo alloy after corrosion tests, the effect of artificial saliva modification on electronic properties of Bego Wirobond C dental alloy was found.

Keywords

electrochemical impedance spectroscopy; CoCrMo dental alloy; pitting corrosion; artificial saliva

Subject

Medicine and Pharmacology, Dentistry and Oral Surgery

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