Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Control of the Gas-Phase Composition (of Atmospheric Pressure Air Plasmas) Using Pulsed Dielectric Barrier Discharges

Version 1 : Received: 12 October 2023 / Approved: 13 October 2023 / Online: 17 October 2023 (05:11:24 CEST)

A peer-reviewed article of this Preprint also exists.

Barni, R.; Alex, P.; Riccardi, C. Pulsed Dielectric Barrier Discharges for Gas-Phase Composition Control: A Simulation Model. Plasma 2023, 6, 735-752. Barni, R.; Alex, P.; Riccardi, C. Pulsed Dielectric Barrier Discharges for Gas-Phase Composition Control: A Simulation Model. Plasma 2023, 6, 735-752.

Abstract

We presents results obtained from the numerical simulation of the gas-phase chemical kinetics in atmospheric pressure air non-equilibrium plasmas. In particular we have addressed the effect of pulsed operation mode of a planar dielectric barrier discharge. As it was conjectured, the large difference in the time scales involved in the fast dissociation of molecules in plasmas and their subsequent reactions to produce stable chemical species, makes the presence of a continuously repeated plasma production stage unnecessary and a waste of electrical power and efficiency. Results on NOx remediation, ozone production, water vapor and ammonia dissociation are discussed. A few comparisons with experimental findings in a dielectric barrier discharge reactor already used for applications is briefly addressed too. Our results clearly indicate a pattern for the optimization of the discharge using a carefully designed repetition rate and duty-cycle.

Keywords

Dielectric Barrier Discharge; Atmospheric Pressure Plasmas; Chemical Kinetics; Plasma Modeling

Subject

Physical Sciences, Fluids and Plasmas Physics

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