Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Comparative Study of Novel Non-Fluorine Polymers as Electron Transport Layer for Perovskite Solar Cell

Version 1 : Received: 5 October 2023 / Approved: 6 October 2023 / Online: 6 October 2023 (08:35:48 CEST)

How to cite: Moiz, S.A.; Alshaikh, M.S.; Alahmadi, A.N.M. Comparative Study of Novel Non-Fluorine Polymers as Electron Transport Layer for Perovskite Solar Cell. Preprints 2023, 2023100321. https://doi.org/10.20944/preprints202310.0321.v1 Moiz, S.A.; Alshaikh, M.S.; Alahmadi, A.N.M. Comparative Study of Novel Non-Fluorine Polymers as Electron Transport Layer for Perovskite Solar Cell. Preprints 2023, 2023100321. https://doi.org/10.20944/preprints202310.0321.v1

Abstract

Perovskite solar cells have shown significant progress, but their commercialization remains hindered by lead-based toxicity. Many nontoxic perovskite-based solar cells have demonstrated potential such as Cs2AgBi0.75Sb0.25Br6, but their power-conversion efficiency is inadequate. To address this issue, some researchers are focusing on emerging acceptor-donor-acceptor'-donor-acceptor (A-DA'D-A) type non-fullerene acceptors (NFAs) for Cs2AgBi0.75Sb0.25Br6 to find effective electron transport layers for high-performance photovoltaic responses with low voltage drops. In this comparative study, four novel A-DA'D-A types NFAs such as BT-LIC, BT-BIC, BT-L4F, and were used as an electron transport layer (ETL) for the proposed devices, FTO/PEDOT: PSS/ Cs2AgBi0.75Sb0.25Br6/ETL/Au. Comprehensive simulations were conducted to optimize the devices. The simulations showed that all optimized devices exhibit photovoltaic responses, with the BT-BIC device having the highest power conversion efficiency (13.2%) and the BT-LIC device having the lowest (6.8%). The BT-BIC as ETL provides fewer interfacial traps and better band alignment, enabling greater open-circuit voltage for efficient photovoltaic responses.

Keywords

Perovskite solar cell; Non-fullerene acceptor (NFA); Electron transport layer, PEDOT:PSS, Cs2AgBi0.75Sb0.25Br6 , BT-BIC, BT-LIC, BT-L4F, and BT-BO-L4F

Subject

Engineering, Electrical and Electronic Engineering

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