Submitted:
28 September 2023
Posted:
03 October 2023
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Abstract
Keywords:
1. Introduction
2. Principles of Intensity-Modulated Fibre Optic Instrumentation
3. Materials and Methods
3.1. Sample Ageing and Standard
- An oven capable of maintaining a constant temperature of 115°C (ASTM D1934-20).
- Beakers
- 18 x 1000ml Pyrex Narrow Mouth Conical Flask
- Natural Ester Transformer Oil (Rapeseed)
- Ageing Timer
- Distilled Water
- Sample containers were meticulously prepared and designated with labels from S1 through S18. Conforming to the guidelines stipulated in ASTM D1934-20 [21], a sampling duration extending a minimum of 96 hours was strictly maintained.
- A volume of 750ml of pristine rapeseed oil was allocated to the container marked S1. In a parallel manner, 750ml of the identical oil specimen was allocated to each of seventeen (17) uncontaminated, narrow-mouthed conical flasks, culminating in a total of eighteen (18) samples with congruent mass. In adherence to ASTM D1934-20, and incorporating an amplification coefficient of 2.333', this paralleled the recommended sampling ratio encompassing a 300ml test specimen situated within a 400ml beaker, achieving an insulating depth proximate to 75mm.
- The temperature of the oven was meticulously calibrated to register 115 ± 1°C, succeeded by a pre-heating intermission spanning 120 seconds.
- Flasks, bearing labels from S2 through S18, were systematically introduced into the oven. Established sampling intervals were maintained. As a precautionary measure, protective hand gear was employed to mitigate thermal injuries. A structured ageing schedule was punctiliously updated, reflecting the progressive removal of samples.
- Upon conclusion of the heating cycle, samples were permitted an adequate cooling period, reverting to ambient conditions.
- The contents housed within flasks S2 to S18 were systematically transferred to their respective, designated containers (see Figure 1). It was imperative to ensure that these containers remained shielded from direct solar exposure.
- A thorough cleaning regimen was implemented for flasks S2 through S18, involving washing, rinsing, and subsequent drying.
3.2. Refractive Index Measurement
- Fresh and Aged Rapeseed Ester Oil
- Bellingham + Stanley Refractometer
- Pipette
- Clean, lint-free cloth
- Distilled Water
- Ethanol
- The refractometer was adjusted to a refractive index value of 1.3333 utilizing distilled water for calibration purposes.
- Ethanol, applied with a lint-free cloth, was used to meticulously cleanse the prism of the refractometer.
- A fresh oil specimen was dispensed onto the prism using a pipette.
- By closing the refractometer's lid, the oil was uniformly distributed across the prism's surface (see Figure 2).
- The refractive index was ascertained by examining through the device's eyepiece.
- The process from steps 2 through 5 was reiterated for samples that had undergone ageing.
- All recorded refractive index values were methodically logged, followed by the thorough cleaning of the refractometer and the testing area.
3.3. Fibre Optic Instrumentation Setup and Data Acquisition System
- Arduino Mega 2560 microcontroller
- Light Emitting Diodes (LED) (Infrared, Red, Blue, and Green)
- Optically Insulated Fabricated vessel for oil
- 1000µm Uncladded Plastic Fibre Optic Cable
- Phototransistor
- Resistors
- PC Workstation + MATLAB Software
- Connecting Cables
- Isopropyl Alcohol
- The opto-electronic setup was completed as illustrated in Figure 3.
- The sensing area of the optical fiber sensor was cleaned with isopropyl alcohol to eliminate any contaminants or residual traces of transformer oil.
- The optical fiber sensor underwent calibration utilizing air for all parameters. The resulting transduced output voltage, as documented in Table 1, served as the calibration reference for deviation adjustments during measurements of both fresh and aged samples.
- 127g of the fresh oil sample was poured into the optically insulated fabricated vessel.
- A settling time of one minute was observed before the transduced output voltage time series data were retrieved from MATLAB Simulink.
- Steps 2 to 5 were repeated for the aged samples.
- The voltage trend data for all samples were recorded and saved for subsequent analysis.
4. Results
4.1. Refractive Index Characterisation
4.2. Sensitivity Analysis
4.2.1. Impact of Optical Source Wavelengths
4.2.2. Noise Response Analysis
4.2.3. Impact of Sensing Lengths
4.3. Repeatability of Results
5. Discussion, Conclusion, and Future Works
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Abbreviations
| ABP | Ageing By-Products |
| DAQ | Data Acquisition System |
| LED | Light Emitting Diode |
| PMMA | Polymethyl Methacrylic |
| POF | Plastic Optical Fiber |
| RI | Refractive Index |
| SOH | State of Health |
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| Sensing Lengths (cm) | LEDs Calibration Voltage (V) | |||
|---|---|---|---|---|
| Green | Red | Blue | Infrared | |
| 1.5 | 4.99 | 4.99 | 4.99 | 4.9093 |
| 2.0 | 4.99 | 4.99 | 4.99 | 4.7488 |
| 3.0 | 4.99 | 4.99 | 4.99 | 4.1563 |
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