Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Annual Cycle of Total Ozone Content in the Southern Hemisphere Using the Chemistry-Climate Model SOCOLv3

Version 1 : Received: 17 September 2023 / Approved: 18 September 2023 / Online: 20 September 2023 (04:53:14 CEST)

How to cite: Zubov, V.; Mironov, A.; Egorova, T.; Rozanov, E. Annual Cycle of Total Ozone Content in the Southern Hemisphere Using the Chemistry-Climate Model SOCOLv3. Preprints 2023, 2023091348. https://doi.org/10.20944/preprints202309.1348.v1 Zubov, V.; Mironov, A.; Egorova, T.; Rozanov, E. Annual Cycle of Total Ozone Content in the Southern Hemisphere Using the Chemistry-Climate Model SOCOLv3. Preprints 2023, 2023091348. https://doi.org/10.20944/preprints202309.1348.v1

Abstract

Several chemistry-climate models (CCM) underestimate the total column ozone (TCO) over the polar region in the Southern Hemisphere during wintertime. To evaluate potential causes of the problem, we exploit CCM SOCOLv3 to study the TCO over Antarctica sensitivity to the: (1) photo-dissociation rates of ozone for large solar zenith angles; (2) rates of the stratospheric heterogeneous reactions, and (3) intensity of the meridional flux into the polar regions due to sub-grid scale mixing processes in the model. Comparisons of the model results with the satellite-based IASI (Infrared Atmospheric Sounder Interferometer) sensor measurements showed that the most important processes for the improvement of the polar ozone simulation results are photolysis and horizontal mixing. The reasonable tuning of these factors has allowed us to improve the model representation of the ozone annual cycle over the southern polar region. The proposed increase of the horizontal mixing can be recommended for the CCMs with relatively low horizontal resolution.

Keywords

ozone layer; chemistry-climate models; photolysis; horizontal transport

Subject

Environmental and Earth Sciences, Atmospheric Science and Meteorology

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