Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Magnetic and Geochemical Properties of Zagreb City Area Soils

Version 1 : Received: 31 August 2023 / Approved: 1 September 2023 / Online: 4 September 2023 (15:26:40 CEST)

A peer-reviewed article of this Preprint also exists.

Frančišković-Bilinski, S.; Peco, J.; Sakan, S.; Đorđević, D.; Inđić, D. Magnetic and Geochemical Properties of Zagreb City Area Soils. Minerals 2023, 13, 1481. Frančišković-Bilinski, S.; Peco, J.; Sakan, S.; Đorđević, D.; Inđić, D. Magnetic and Geochemical Properties of Zagreb City Area Soils. Minerals 2023, 13, 1481.

Abstract

The study was performed to get the first insight of distribution of the low field volume magnetic susceptibility (MS) throughout the Zagreb city area, based on in-situ field measurements. Most interesting locations were selected for soil sampling and geochemical content was determined using ICP-OES. A geostatistical approach was applied on MS and geochemical results. Median value of 0.245 x 10-3 SI units is proposed to be used as relevant average MS value in Zagreb area. Mean concentrations of heavy metals in Zagreb soils (in µg/g) are: Pb (36.82), Zn (87.77), Cu (30.84), Cd (0.66), Cr (29.04), Co (11.89) and Ni (28.40), being relatively low in comparison with Croatian legislation and with European and world average. Boxplot analyses showed that 45% of studied elements do not show any anomaly, while the rest of elements mostly show only one weak anomaly and they are located at the same sites as MS anomalies. Statistical analysis found significant correlations between MS and following elements: Cd, Co, Fe, Mn, Na, Pb, Sb and Zn. In-situ MS measurements proved to be an efficient tool for initial screening of large areas in terms of elevated heavy elements concentrations, enabling cheap and fast assessment of state of environment.

Keywords

magnetic susceptibility; geochemistry; Zagreb urban area (Croatia); soils; anthropogenic influence; geological background

Subject

Environmental and Earth Sciences, Geophysics and Geology

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