Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Effortless One-Pot Two-Step Creation of NiS-NiO/S-g-C3N4: The Next Generation Photocatalyst for Green C(sp3)-F Bond Activation and Coenzyme Regeneration

Sanjana Kumari
,
Rajesh K. Yadav
* ,
Satyam Singh
ORCID logo ,
Rehana Shahin
,
Suresh Kumar Pandey
,
Kamini Singh
,
Atul Partap Singh
,
Navneet Kumar Gupta
,
Dhanesh Tiwary
,
D. K. Dwivedi
*
Version 1 : Received: 12 July 2023 / Approved: 12 July 2023 / Online: 13 July 2023 (12:20:04 CEST)

How to cite: Kumari, S.; Yadav, R.K.; Singh, S.; Shahin, R.; Pandey, S.K.; Singh, K.; Singh, A.P.; Gupta, N.K.; Tiwary, D.; Dwivedi, D.K. Effortless One-Pot Two-Step Creation of NiS-NiO/S-g-C3N4: The Next Generation Photocatalyst for Green C(sp3)-F Bond Activation and Coenzyme Regeneration. Preprints 2023, 2023070866. https://doi.org/10.20944/preprints202307.0866.v1 Kumari, S.; Yadav, R.K.; Singh, S.; Shahin, R.; Pandey, S.K.; Singh, K.; Singh, A.P.; Gupta, N.K.; Tiwary, D.; Dwivedi, D.K. Effortless One-Pot Two-Step Creation of NiS-NiO/S-g-C3N4: The Next Generation Photocatalyst for Green C(sp3)-F Bond Activation and Coenzyme Regeneration. Preprints 2023, 2023070866. https://doi.org/10.20944/preprints202307.0866.v1

Abstract

Fluorinated compounds and co-enzymes are being widely researched and employed throughout research community because of their versatile physical, chemical and biological properties. In this work, we synthesized NiS-NiO/S-g-C3N4, a highly effective photocatalyst for C(sp3)-F bond activation and the regeneration of coenzyme (1,4-NADH) employing a new and ecologically acceptable route. The obtained photocatalyst exhibited important photocatalytic properties, such as good solar light harvesting ability, suitability of the optical band-gap, and facilitating efficient charge migrations. As a result, the newly designed NiS-NiO/S-g-C3N4 photocatalyst shows the excellent yield for regenerations of 1,4-NADH (51%). Further, a method of combining C(sp3)-F bond activation with photocatalysis has been demonstrated that represents a very powerful and sustainable approach, that can be a major breakthrough for the field of pharmaceutical.

Keywords

NiS-NiO/S-g-C3N4 photocatalyst 1; C(sp3)-F Bond Activation 2; Regeneration of Coenzyme 3; Solar Light 4; Selectfluor 5

Subject

Chemistry and Materials Science, Applied Chemistry

Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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