Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Progress on Designing Artificial Solid Electrolyte Interphases for Dendrite Free Sodium Metal Anodes

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These authors contributed equally as co-first author.
Version 1 : Received: 22 May 2023 / Approved: 23 May 2023 / Online: 23 May 2023 (03:30:40 CEST)

A peer-reviewed article of this Preprint also exists.

Shi, P.; Wang, X.; Cheng, X.; Jiang, Y. Progress on Designing Artificial Solid Electrolyte Interphases for Dendrite-Free Sodium Metal Anodes. Batteries 2023, 9, 345. Shi, P.; Wang, X.; Cheng, X.; Jiang, Y. Progress on Designing Artificial Solid Electrolyte Interphases for Dendrite-Free Sodium Metal Anodes. Batteries 2023, 9, 345.

Abstract

The nature abundant sodium metal is proposed as ideal anode materials for advanced batteries due to its high specific capacity of 1166mAh g-1 and low redox potential of -2.71V. However, the uncontrollable dendritic Na formation and low coulombic efficiency are still major obstacles for applications. Notably, the unstable and inhomogeneous solid electrolyte interphase (SEI) is recognized to be the root cause. As SEI layer plays a critical role in regulating uniform Na deposition and improving cycling stability, researches on SEI modification, especially the artificial SEI modifications has been extensively investigated recently. In this regard, we discussed the advances on artificial interface engineering from the aspects of inorganic, organic and hybrid inorganic/organic protective layers. Finally, we also highlighted the conclusions and key prospects for further investigations. We hope this review can provide a new insight for sodium metal protection.

Keywords

Sodium metal; artificial SEI; dendrite formation; batteries

Subject

Chemistry and Materials Science, Electrochemistry

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