Preprint Communication Version 1 Preserved in Portico This version is not peer-reviewed

Simple Preparation of a Unique Ionic Liquid/Deep Eutectic Solvent and β-Cyclodextrin Composite Discs and Its Use To Capture Hazardous Substances From Water

Version 1 : Received: 18 May 2023 / Approved: 19 May 2023 / Online: 19 May 2023 (04:04:11 CEST)

A peer-reviewed article of this Preprint also exists.

Guo, Y.; Liu, N.; Chen, H.; Ali, A.; Toufouki, S.; Yao, S. Simple Preparation of a Unique Ionic Liquid/Deep Eutectic Solvent and β-Cyclodextrin Composite Discs and Its Use to Capture Hazardous Substances from Water. Separations 2023, 10, 357. Guo, Y.; Liu, N.; Chen, H.; Ali, A.; Toufouki, S.; Yao, S. Simple Preparation of a Unique Ionic Liquid/Deep Eutectic Solvent and β-Cyclodextrin Composite Discs and Its Use to Capture Hazardous Substances from Water. Separations 2023, 10, 357.

Abstract

With the development of health service, animal husbandry, aquaculture and chemical industry, more and more pollutants are discharged into the water environment, including antibiotics and heavy metal ions. These hazard substances pose a great threat to environment safety and human health. As two kinds of new green solvents, ionic liquids (ILs) and deep eutectic solvents (DESs) are widely used in various fields including separation and environmental engineering, which are attracting huge attention from academia and industry. In this study, the optimal ionic liquid and deep eutectic solvent were selected and their complex with β-cyclodextrin (β-CD) were firstly prepared by simple and effective inclusion way. After necessary characterization and analysis, two kinds of complex were applied to prepare a special sorbent disc with two different sides by adding diluent (excipient) and pressing under 5~15 MPa. As the result, the IL and DES could be stably immobilized on the disc and play the key role in selective adsorption for targets. Besides that, the experiments of different hazardous substances achieved the expected results. Based on this study, the complex disc showed a lot of merits in the separation performance, easy preparation and use, simple operation, and good stability. It was believed to be a useful tool for water purification and detection.

Keywords

ionic liquid; deep eutectic solvent; cyclodextrin; sorbent disc; water environment

Subject

Chemistry and Materials Science, Chemical Engineering

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