Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Synthesis and Characterization of Nd:YAG Ceramics for Laser Applications

Version 1 : Received: 16 May 2023 / Approved: 17 May 2023 / Online: 17 May 2023 (12:56:53 CEST)

A peer-reviewed article of this Preprint also exists.

Echartea-Reyes, O.A.; Vázquez-García, G.V.; Castillo-Robles, J.A.; López-Hernández, J.; Calles-Arriaga, C.A.; Pech-Rodríguez, W.J.; Rocha-Rangel, E. Synthesis and Characterization of Nd:YAG Ceramics for Laser Applications. Ceramics 2023, 6, 1655-1666. Echartea-Reyes, O.A.; Vázquez-García, G.V.; Castillo-Robles, J.A.; López-Hernández, J.; Calles-Arriaga, C.A.; Pech-Rodríguez, W.J.; Rocha-Rangel, E. Synthesis and Characterization of Nd:YAG Ceramics for Laser Applications. Ceramics 2023, 6, 1655-1666.

Abstract

Materials known as Nd:YAG are crystalline materials of the cubic system made from neodymium-doped yttrium aluminum garnet, which among others, have excellent optical properties. Nd:YAG four-level laser devices are highly used in both the health and industrial sectors. In this study, a simple and inexpensive alternative to manufacturing Nd:YAG materials through solid state reactions following powder processing routes was proposed. For this, an intense mixture of the precursor materials (Al2O3 and Y2O3) was carried out, followed by the addition of neodymium atoms to improve the optical properties of the resulting material. High energy mechanical mixing of the precursor powders resulted in submicron particles, with good size distributions of the powders. The advance of YAG formation was monitored by intermediate phase formation during heat treatment through interrupted tests at different temperatures and analysis by X-ray diffraction. From this analysis, it was found that reaction for the formation of the desired YAG is completed at 1500°C. Fourier-transform infrared spectroscopy analyses determined the presence of functional groups corresponding to the YAG. Finally, the study by optical emission spectroscopy showed wavelengths in agreement with the electronic structure of the elements of the synthesized Nd:YAG.

Keywords

Nd-YAG; Laser; Optical characterization

Subject

Chemistry and Materials Science, Ceramics and Composites

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