Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Effect of Nanoparticle Interaction on Structural, Conducting and Sensing Properties of Mixed Metal Oxides

Version 1 : Received: 12 May 2023 / Approved: 15 May 2023 / Online: 15 May 2023 (03:34:15 CEST)

A peer-reviewed article of this Preprint also exists.

Trakhtenberg, L.I.; Ikim, M.I.; Ilegbusi, O.J.; Gromov, V.F.; Gerasimov, G.N. Effect of Nanoparticle Interaction on Structural, Conducting and Sensing Properties of Mixed Metal Oxides. Chemosensors 2023, 11, 320. Trakhtenberg, L.I.; Ikim, M.I.; Ilegbusi, O.J.; Gromov, V.F.; Gerasimov, G.N. Effect of Nanoparticle Interaction on Structural, Conducting and Sensing Properties of Mixed Metal Oxides. Chemosensors 2023, 11, 320.

Abstract

The review analyzes the studies published mainly in the last 10-15 years, on the synthesis, structure, and sensor properties of semiconductor nanocomposites. Particular attention is paid to the interaction between nanoparticles of the sensitive layer and its effect on the structure, sensitivity, and selectivity of semiconductor sensor systems. Various mechanisms are considered of interaction between nanoparticles in metal oxide composites including incorporation of metal ions of one component into the structure of another, heterocontacts between different nanoparticles, and core-shell systems, as well as their influence on the characteristics of gas sensors. The experimental data and studies on the modeling of charge distribution in semiconductor nanoparticles, which determine the conductivity and sensor effect in one- and two-component systems, are also discussed. It is shown that the model which considers the interactions of nanoparticles best describes the experimental results. Some mechanisms of detection selectivity are considered in the conclusion.

Keywords

mixed metal oxide sensors; nanoparticles interaction; morphology; structure; sensing properties

Subject

Physical Sciences, Chemical Physics

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