Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Reasoning and Logical-Proofs of the Fundamental Laws: ‘No Hope’ for the Challengers of the Second Law of Thermodynamics

Version 1 : Received: 4 May 2023 / Approved: 5 May 2023 / Online: 5 May 2023 (08:21:49 CEST)

A peer-reviewed article of this Preprint also exists.

Kostic, M. Reasoning and Logical Proofs of the Fundamental Laws: “No Hope” for the Challengers of the Second Law of Thermodynamics. Entropy 2023, 25, 1106. Kostic, M. Reasoning and Logical Proofs of the Fundamental Laws: “No Hope” for the Challengers of the Second Law of Thermodynamics. Entropy 2023, 25, 1106.

Abstract

This comprehensive treatise is written for the special occasion of the author’s 70th birthday. It presents his lifelong endeavors and reflections with original reasoning and re-interpretations of the most critical and misleading issues in thermodynamics; since now, we have the advantage to look at the historical developments more comprehensively and objectively than the pioneers. Starting from Carnot (grand-father of thermodynamics-to-be) to Kelvin and Clausius (fathers of thermodynamics), and other followers, the most relevant issues are critically examined and put in historical and contemporary perspective. From original reasoning of energy forcing and displacement to logical-proofs of the fundamental laws, to ubiquity of thermal motion and heat, and indestructibility of entropy, including new concept of “thermal roughness” and inevitability of dissipative irreversibility, to “dissecting Carnot true reversible-equivalency” and critical concept of “Carnot-Clausius heat-work equivalency (CCHWE)” regarding interchangeability of heat and work, and to demonstrating “no hope” for the “challengers” of the Second Law of thermodynamics, among others, are offered. It is hoped that the novel contributions presented will enhance comprehension and resolve some of the fundamental issues, as well as promote collaboration and future progress.

Keywords

Thermodynamics; Fundamental Laws; Second Law of Thermodynamics; Carnot Equality; Carnot-Clausius Heat-Work Equivalency; Thermal Roughness; Irreversibility; Work Potential and Exergy; Perpetual Motion Machines

Subject

Physical Sciences, Thermodynamics

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