Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Synergistic Improvement of Flame Retardancy and Mechanical Properties of Epoxy/Benzoxazine/Aluminum Trihydrate Adhesive Composites

Version 1 : Received: 17 April 2023 / Approved: 18 April 2023 / Online: 18 April 2023 (05:07:10 CEST)

A peer-reviewed article of this Preprint also exists.

Sung, K.-S.; Kim, N. Synergistic Improvement of Flame Retardancy and Mechanical Properties of Epoxy/Benzoxazine/Aluminum Trihydrate Adhesive Composites. Polymers 2023, 15, 2452. Sung, K.-S.; Kim, N. Synergistic Improvement of Flame Retardancy and Mechanical Properties of Epoxy/Benzoxazine/Aluminum Trihydrate Adhesive Composites. Polymers 2023, 15, 2452.

Abstract

Epoxy was blended with benzoxazine resin and aluminum trihydrate (ATH) additive to render flame retardancy while maintaining mechanical properties. The ATH was modified using three different silane coupling agents and then added to 60/40 epoxy/benzoxazine mixtures. The effect of blend compositions and surface modification on flame retardant and mechanical properties of the composites was investigated by UL94, tensile, and shear tests. Resin mixtures containing more than 40 wt% benzoxazine revealed a UL94 V-1 rating with enhanced tensile and shear strength. Upon addition of 20 wt% ATH to 60/40 epoxy/benzoxazine, a V-0 rating was achieved. The lowered tensile and adhesive properties of the composites in the presence of ATH were improved by modifying the ATH surface using silane coupling agents.

Keywords

adhesive; aluminum trihydrate; benzoxazine; flame retardancy; silane coupling agent

Subject

Chemistry and Materials Science, Polymers and Plastics

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