Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-SC Alloy

Version 1 : Received: 13 April 2023 / Approved: 14 April 2023 / Online: 14 April 2023 (03:19:33 CEST)

A peer-reviewed article of this Preprint also exists.

Henle, R.; Dölling, J.; Prahl, U.; Nandi, G.; Zilly, A. DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy. Materials 2023, 16, 3462. Henle, R.; Dölling, J.; Prahl, U.; Nandi, G.; Zilly, A. DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy. Materials 2023, 16, 3462.

Abstract

The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section reduced cold-rolled, supersaturated specimens were tested at non-isothermal DSC runs at up to five different heating rates. The DSC results showed that cold deformation significantly accelerated the precipitation process in the binary alloy, leading to a decrease in the initial and peak temperatures of the exothermic reactions. The activation energies calculated with the Kissinger method, indicated that the precipitation activation energy decreased with increasing cold deformation. The findings of this study provide worthy implications to further optimize the processing of Cu-Sc alloys with improved mechanical properties.

Keywords

copper-scandium CuSc; copper alloy; differential scanning calorimetry DSC; precipitation kinetics; cold-working; cold-rolling; activation energy; Kissinger method

Subject

Chemistry and Materials Science, Materials Science and Technology

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