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Anomalous Diffusion With an Apparently Negative Diffusion Coefficient in a One-Dimensional Quantum Molecular Chain Model

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Submitted:

03 February 2021

Posted:

04 February 2021

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Abstract
An interesting anomaly of the diffusion process with an apparently negative diffusion coefficient defined through the mean-square displacement in a one-dimensional quantum molecular chain model is shown. Nevertheless, the system satisfies the H-theorem, so that the second law of thermodynamics is satisfied. The reason why the “diffusion constant” becomes negative is due to the effect of the phase mixing process, which is a characteristic result of the one-dimensionality of the system. We illustrate the situation where this negative “diffusion constant” appears.
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Subject: 
Physical Sciences  -   Acoustics
Copyright: This open access article is published under a Creative Commons CC BY 4.0 license, which permit the free download, distribution, and reuse, provided that the author and preprint are cited in any reuse.

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