Feng, L.; Li, W.; Bao, J.; Zheng, Y.; Li, Y.; Ma, Y.; Yang, K.; Qiao, Y.; Wu, A. Synthesis and Luminescence Properties of Core-Shell-Shell Composites: SiO2@[email protected]2 and SiO2@[email protected]2. Nanomaterials2019, 9, 189.
Feng, L.; Li, W.; Bao, J.; Zheng, Y.; Li, Y.; Ma, Y.; Yang, K.; Qiao, Y.; Wu, A. Synthesis and Luminescence Properties of Core-Shell-Shell Composites: [email protected]@SiO2 and [email protected]@SiO2. Nanomaterials 2019, 9, 189.
Two novel core-shell composites [email protected], [email protected] with SiO2 as the core and terbium organic complex as the shell, were successfully synthesized. The terbium ion was coordinated with organic ligand forming terbium organic complex in the shell layer. The bi-functional organosilane ((HOOC)2C6H2(CONH(CH2)3Si(OCH2CH3)3)2 (abbreviated as PMDA-Si) was used as the first ligand and phen as the second ligand. Furthermore, the silica-modified [email protected]@SiO2, [email protected]@SiO2 core-shell-shell composites were also synthesized by sol–gel chemical route. An amorphous silica shell was coated around the [email protected] and [email protected] core-shell composites. The core-shell and core-shell-shell composites both exhibited excellent luminescence in solid state. The luminescence of core-shell-shell composites was stronger than that of core-shell composites. Meanwhile, an improved luminescence stability property for the core-shell-shell composites was found in the aqueous solution. The core-shell-shell composites exhibited bright luminescence, high stability, long lifetime, and good solubility, which may present potential applications in the field of bio-medical.
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