Chitosan Derivatives: Introducing New Functionalities with a Controlled Molecular Architecture for Innovative Materials †

Waldo M. Argüelles-Monal; Jaime Lizardi-Mendoza; Daniel Fernández-Quiroz; Maricarmen T. Recillas-Mota; Marcelino Montiel-Herrera

doi:10.20944/preprints201803.0005.v1

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preprints.org > materials science > polymers & plastics > doi: 10.20944/preprints201803.0005.v1

Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Chitosan Derivatives: Introducing New Functionalities with a Controlled Molecular Architecture for Innovative Materials ^†

Waldo M. Argüelles-Monal

^* ,

Jaime Lizardi-Mendoza

^* ,

Daniel Fernández-Quiroz

Maricarmen T. Recillas-Mota

Marcelino Montiel-Herrera

^†

Dedicated to the memory of the late Prof. Ruth D. Henríques, who introduced me to research on chitin [WMAM]

Version 1 : Received: 28 February 2018 / Approved: 1 March 2018 / Online: 1 March 2018 (07:13:47 CET)

A peer-reviewed article of this Preprint also exists.

Argüelles-Monal, W.M.; Lizardi-Mendoza, J.; Fernández-Quiroz, D.; Recillas-Mota, M.T.; Montiel-Herrera, M. Chitosan Derivatives: Introducing New Functionalities with a Controlled Molecular Architecture for Innovative Materials. Polymers 2018, 10, 342. Argüelles-Monal, W.M.; Lizardi-Mendoza, J.; Fernández-Quiroz, D.; Recillas-Mota, M.T.; Montiel-Herrera, M. Chitosan Derivatives: Introducing New Functionalities with a Controlled Molecular Architecture for Innovative Materials. Polymers 2018, 10, 342.

DOI: 10.3390/polym10030342

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Abstract

The functionalization of polymeric substances is of great interest for the development of innovative materials for advanced applications. For many decades, the functionalization of chitosan has been a convenient way to improve its properties with the aim to prepare new materials with specialized characteristics. In the present article, we summarize the latest methods for the modification and derivatization of chitin and chitosan, trying to introduce specific functional groups under experimental conditions, which allow a control over the macromolecular architecture. This is motivated because an understanding of the interdependence between chemical structure and properties is an important condition for proposing innovative materials. New advances in methods and strategies of functionalization such as click chemistry approach, grafting onto copolymerization, coupling with cyclodextrins and reactions in ionic liquids are discussed.

Keywords

chitin; chitosan; derivatization; controlled functionalization, click chemistry; graft copolymer; cyclodextrin; dendrimer; ionic liquids

Subject

MATERIALS SCIENCE, Polymers & Plastics

Copyright: This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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