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Effect of Alkane Chain Length on Crystallization in Emulsions during Supercooling in Quiescent Systems and under Mechanical Stress

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Submitted:

15 November 2017

Posted:

16 November 2017

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Abstract
Crystallization behavior of hexadecane (C16H34), octadecane (C18H38), eicosane (C20H42), and docosane (C22H46) dispersions of similar mean droplet diameter (x50.2 ≈ 15 µm) was investigated in quiescent systems and compared to crystallization under mechanical stress. In quiescent systems, the required supercooling decreased with increasing chain length of the alkanes to initiate crystallization. Crystallization of alkane dispersions under mechanical stress resulted in similar onset crystallization supercooling, as during quiescent crystallization. Increase of mechanical stress did not affect the onset crystallization supercooling within alkane dispersions.
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Subject: Chemistry and Materials Science  -   Applied Chemistry
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