The Semiconductor and Liquid Assisted Photothermal Effect (SLAPE)” concept was employed for the first time in this study to generate electricity from sunlight. In SLAPE process, a semiconducting material is immersed completely in a stable organic solvent to capture the complete sunlight reaching the earth surface and to turn it into the heat-energy that can be eventually converted into electricity by using Organic Rankine Cycle (ORC) with the help of a heat engine and electric generator. In this investigation, the SLAPE solar panels were fabricated with two top and bottom chambers separated by thin thermally conducting metal sheet (Cu or Al). Multi-crystalline silicon photovoltaic cells (SPVCs) in conjunction with -butyrolactone were employed to capture the sunlight, and a low-boiling point dichloromethane (DCM) solvent was employed as a working fluid to capture the in situ generated heat energy from sunlight. Upon exposure to the natural sunlight, the 21 numbers of SPVCs together with about 2 litres -butyrolactone containing one square meter area SLAPE solar panel has generated about 17 V when integrated with a laboratory model reciprocally moved steam engine and a custom-made electric generator, whereas, a commercial SPVC solar panel with 21 number SPVCs generate a maximum voltage of 11 V. The theoretical background governing the SLAPE solar panels, the necessity for their invention and the proof of concept of SLAPE solar panels have been thoroughly presented and discussed and established in this article.