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Preprint ARTICLE | doi:10.20944/preprints202310.0521.v1

An Unusual Rearrangement of Pyrazole Nitrene and Ring Opening/Recyclization Cascade: Formal CH-Acetoxylation and Azide/Amine Conversion without External Oxidants and Reductants

Elena Chugunova, Almir S Gazizov, Daut Islamov, Victoria Matveeva, Alexander Burilov, Nurgali Akylbekov, Alexey Dobrynin, Rakhmetulla Zhapparbergenov, Nurbol Appazov, Beauty K. Chabuka, Kimberley Christopher, Daria I. Tonkoglazova, Igor Alabugin

Subject: Chemistry And Materials Science, Organic Chemistry Keywords: furoxan; 1H-pyrazole; nitrene; fragmentation; cyclization

Online: 9 October 2023 (10:24:39 CEST)

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