At the anode, hydrogen gas dissociates into protons (H⁺) and electrons. Protons are conducted across the polymer electrolyte membrane to the cathode, while electrons travel through the external circuit, performing electrical work. At the cathode, protons, electrons, and oxygen combine to produce water as the sole reaction product. This reaction corresponds to a theoretical open-circuit voltage of 1.23 V; in practice, cell voltages under load typically fall within the range of 0.6–0.8 V. A PEMFC stack consists of the following principal components:
Gas Diffusion Layers (GDLs): GDLs distribute reactant gases uniformly over the catalyst layer surface and facilitate product water removal. They are typically fabricated from carbon paper or carbon cloth.
2.2. Hydrogen Storage Technologies
The most widely deployed hydrogen storage method in current UAV systems is compressed gaseous storage in high-pressure cylinders, classified into five structural categories [
17]:
Type I (All-Metal — Steel): Operating pressure: 17.5–20 MPa; gravimetric hydrogen fraction: ~1%; service life: 15 years. Heaviest option has limited structural safety margins.
Type II (Metal Liner with Hoop Winding): Operating pressure: 26.3–30 MPa; gravimetric hydrogen fraction: ~1.5%; service life: 15 years.
Type III (Metal Liner with Full Composite Overwrap): Operating pressure: 30–70 MPa; gravimetric hydrogen fraction: 2.4–4.1%; storage density: 35–40 g/L; service life: 15–20 years. Suitable for mini and tactical UAV applications.
Type IV (Polymer Liner with Carbon Fiber Composite): Operating pressure: >70 MPa; gravimetric hydrogen fraction: 2.5–5.7%; storage density: 38–40 g/L; service life: 15–20 years. Type IV tanks are 39.2% lighter than Type I equivalents and represent the one of preferred options for UAV integration.
Type V (Linerless Carbon Fiber Composite): Operating pressure: >72 MPa; gravimetric hydrogen fraction: 8–12%; storage density: 25–40 g/L; service life: 15–20+ years. Type V tanks are 10-30% lighter than Type IV equivalents and represent the best option for UAV integration.
The selection between Type III and Type IV involves a trade-off between gravimetric efficiency and long-term structural integrity. While Type IV offers superior mass performance, critical for mini-class UAVs with MTOW below 2 kg, the polymer liner undergoes hydrogen-induced permeation more readily than metallic liners, and micro-crack propagation in the carbon fiber overwrap under cyclic pressurization remains an open durability question with direct implications for operational safety [
4,
17]. This implies that UAV-specific qualification protocols must include coupled vibration–pressure fatigue testing at representative blade-pass frequencies, distinct from the fill-cycle-only methodology of current automotive standards (EC79, ISO 15869) — a gap that requires dedicated test infrastructure and updated certification guidance from EASA and FAA.
Currently, Type IV hydrogen storage tanks are employed by several automotive manufacturers, including BMW, Toyota, Hyundai, and Honda, Nissan [
18,
19,
20,
21,
22,
23]. These tanks comprise a polymer liner fully wrapped with carbon fibre-reinforced polymer (CFRP) composites [
20,
21,
22,
23,
24,
25,
26,
27]. In contrast, Type V tanks [
28,
29,
30,
31,
32,
33,
34]are linerless structures fabricated entirely from fibre-reinforced polymer composites, making them significantly lighter than Type IV tanks. Although Type V technology remains under development and has not yet reached full technological maturity, these tanks are expected to withstand operating pressures of up to 720 bar while offering substantial reductions in structural weight.
Figure 4 illustrates the different types of hydrogen storage tanks currently available.
Despite the capability of Type IV tanks to withstand high internal pressures and satisfy the stringent requirements of automotive applications [
19], they remain relatively expensive and insufficiently lightweight for weight-sensitive sectors such as aerospace. Consequently, Type V tanks have become a major focus of research, particularly for aviation and unmanned aerial vehicle (UAV) applications [
35,
36,
37,
38], in addition to the automotive industry. Owing to their ultra-lightweight design, Type V tanks are anticipated to provide a cost-effective, safe, and mass-producible solution while enabling conformal geometries that can be integrated efficiently into complex structures [
39]. These characteristics make Type V tanks particularly attractive for aerospace applications, especially drones and UAVs, where several manufacturers have already initiated development programmes aimed at their adoption [
35,
36,
37,
38,
40].
Nevertheless, several critical challenges continue to hinder the widespread implementation of Type V hydrogen storage systems. One of the most significant issues is hydrogen permeation [
41,
42,
43,
44,
45,
46,
47,
48,
49], which arises from the exceptionally small molecular size and low molecular weight of hydrogen. These characteristics enable hydrogen molecules to diffuse through the polymer matrix and, in some cases, along fibre-matrix interfaces within the composite wall. Such diffusion may eventually lead to hydrogen leakage, progressive degradation of the composite constituents, and a consequent reduction in the structural integrity and storage efficiency of the tank [
50,
51].
Permeation is a physical transport phenomenon defined as the steady-state diffusion of atoms or molecules through a solid material under a pressure gradient [
52]. The permeation process generally consists of three sequential stages [
45]: (1) absorption of hydrogen at the material surface, (2) diffusion through the material, and (3) desorption from the opposite surface. Although permeation is unavoidable to some extent, prolonged hydrogen exposure can significantly deteriorate the mechanical performance of composite materials, particularly those employed in Type V tanks. Under sustained internal pressure, the polymer matrix is susceptible to microcrack initiation, which may progressively evolve into fibre-matrix interfacial debonding as indicated in
Figure 5. Continued damage accumulation can subsequently lead to hydrogen leakage, laminate delamination, fibre fracture, and ultimately catastrophic failure of the pressure vessel [
53,
54]. Considering the highly flammable nature of hydrogen, any leakage poses a significant safety hazard.
Another degradation mechanism observed in laminated composite hydrogen tanks is blistering, which refers to the formation of gas-filled cavities within the composite structure. Blistering occurs when hydrogen diffuses into the composite during repeated filling and emptying cycles and becomes trapped within the material, generating localized gas pockets and additional internal stresses [
53]. Over time, these cavities may grow in size, thereby compromising the structural integrity of the tank [
54,
55,
56]. Furthermore, cavity formation disrupts the uniform stress distribution within the laminate, creating localized stress concentrations [
57] that promote interlaminar delamination and further structural degradation [
50,
51].
Hydrogen embrittlement represents another critical degradation mechanism affecting composite hydrogen storage systems. During long-term exposure, hydrogen diffuses into the composite constituents, particularly the polymer matrix and fibre-matrix interface, altering the mechanical response of the material from relatively ductile to increasingly brittle behaviour [
58]. Elevated temperatures generated during rapid refuelling accelerate hydrogen diffusion into the composite wall, thereby intensifying the embrittlement process and further reducing the long-term durability and reliability of the storage tank.
This challenge compels tank designers to develop robust and reliable designs that minimize the risk of catastrophic failure. Achieving this objective requires a comprehensive understanding of the fundamental behaviour of laminated composite materials, including the constituent fibres, polymer matrix, and the adhesive systems employed in the assembly of the tank components.
As the mainstream materials for hydrogen tanks type V, laminated composite materials have been increasingly adopted in the aerospace and automotive industries owing to their high specific stiffness and strength, low density, excellent fatigue performance, and superior corrosion and damage resistance [
59,
60,
61,
62,
63]. In modern commercial aircraft, such as the Airbus A380 and the Boeing 787 Dreamliner, composite materials account for approximately 50% of the structural weight and are extensively employed in both primary and secondary load-bearing components. Their widespread adoption highlights the pivotal role of composite materials in the design of next-generation aircraft. Their outstanding strength-to-weight ratio enables significant weight reduction, leading to improved aerodynamic efficiency, enhanced manoeuvrability, lower fuel consumption, and reduced operating costs [
64].
With respect to Type V hydrogen storage tanks, extensive knowledge of laminated composite materials, adhesive bonding technologies, and pressure vessel design is essential, ranging from the fundamental mechanical behaviour of constituent materials to advanced manufacturing and assembly techniques [
65]. Since hydrogen permeation and leakage remain the principal challenges associated with linerless composite pressure vessels, considerable research has focused on developing effective mitigation strategies. One promising approach involves the application of polymeric barrier materials [
66,
67] as internal surface layers on the composite laminate to reduce hydrogen permeation. In addition, advanced adhesive bonding technologies have the potential to minimize leakage at critical interfaces, particularly in joints connecting the metallic boss assembly to the composite tank wall [
68,
69,
70,
71].
The design of Type V tanks must also account for the mechanics of thin- and thick-walled pressurised vessels [
72,
73]. Furthermore, the thermodynamic behaviour of hydrogen during rapid filling and discharge cycles within the confined tank volume is recognised as a critical phenomenon that directly influences the structural response of the composite materials [
70,
71]. The combined effects of pressure, temperature, and hydrogen diffusion necessitate a comprehensive understanding of the material behaviour under a wide range of environmental and service conditions.
Reliable material characterisation constitutes the foundation of robust structural design. Accurate determination of the mechanical properties of structural adhesives used in the assembly of Type V tanks, particularly for bonding the metallic boss to the composite shell, is essential because these properties serve as critical input parameters for numerical simulations and structural integrity assessments. Consequently, experimental techniques developed for the tensile [
74] and shear [
75] characterisation of structural adhesives must provide reliable and reproducible stress–strain data, as inaccuracies in the measured material properties can significantly compromise the accuracy of design predictions.
Because structural adhesives exhibit a broad spectrum of mechanical behaviours, no single experimental methodology is universally applicable. For example, non-contact optical measurement techniques are generally preferred for determining the tensile stress–strain response of highly flexible adhesives, whereas conventional contact extensometers are often suitable for relatively stiff adhesives. Similarly, accurate measurement of the shear behaviour requires carefully designed experimental procedures, with the testing methodology depending on whether the adhesive is evaluated as a thin bonded layer [
76] or as a bulk material [
75]. Appropriate selection of structural adhesives is equally important because joint performance strongly depends on the loading mode and stress distribution. Ductile adhesives, despite exhibiting lower ultimate strengths, often outperform brittle adhesives in joints containing significant stress concentrations owing to their superior strain-to-failure and enhanced capacity for stress redistribution [
77].
Equally important is the accurate characterisation of the laminated composite materials that constitute the primary load-bearing structure of Type V tanks. Composite laminates incorporating fibre orientations of ±θ are commonly employed to achieve the required balance between hoop and axial load-carrying capacity. Reliable experimental characterisation over both low-stress [
78] and high-stress regimes [
79] is therefore essential for obtaining dependable design data. Furthermore, a comprehensive understanding of the behaviour of adhesively bonded composite joints in various configurations [
65] provides valuable insight for the design of hydrogen storage systems, where bonded assemblies are widely employed. The mechanical response of these joints under quasi-static, fatigue, and impact loading [
80,
81,
82,
83,
84], as well as under different environmental conditions, including elevated temperatures and humidity [
85,
86], represents critical information for predicting the long-term durability, safety, and reliability of Type V hydrogen storage tanks.
Although hydrogen possesses the highest gravimetric energy density of all conventional fuels, its inherently low volumetric energy density necessitates storage at very high pressures, resulting in a significant demand for storage volume [
87]. Consequently, efficient utilisation of the available space within a vehicle has become a major design challenge, particularly in weight-sensitive applications such as aerospace. This challenge has stimulated the development of Type V linerless composite pressure vessels capable of adopting conformal geometries that maximise both gravimetric and volumetric storage efficiencies [
31,
88,
89].
Conventional high-pressure hydrogen storage vessels are predominantly cylindrical or spherical because these geometries minimise stress concentrations under internal pressure [
35,
36,
37,
38]. However, such shapes utilise the available installation volume inefficiently, leaving considerable unused space within the vehicle architecture (see
Figure 6) To overcome this limitation, increasing attention has been directed towards the development of conformal Type V pressure vessels, such as rectangular-prism or other non-axisymmetric geometries, which can be integrated more effectively into the structural layout of vehicles (see
Figure 7). These designs have the potential to maximise the utilisation of available space while simultaneously reducing overall vehicle weight and improving storage efficiency [
40,
90].
Despite the growing interest from stakeholders, particularly within the aerospace sector, publicly available research on conformal Type V hydrogen tanks remains limited [
23,
42]. Nevertheless, the increasing commitment of aerospace industries to hydrogen-powered propulsion systems has intensified research efforts aimed at integrating high-pressure hydrogen storage into aircraft structures [
42]. Such integration enables innovative vehicle architectures in which the storage tanks become an inherent part of the airframe rather than separate payload components. As illustrated in
Figure 7, the future hydrogen-powered aircrafts are expected to incorporate storage vessels with geometries that complement the overall aerodynamic profile, thereby improving aerodynamic efficiency, reducing drag, and enhancing both safety and structural integration.
This design philosophy represents a fundamental departure from conventional cylindrical pressure vessels. Rather than functioning solely as energy storage devices, conformal composite tanks can simultaneously serve as structural members within the airframe. One representative example is the integration of hydrogen storage tanks into the wing structures of light aircraft (
Figure 7), where the tanks not only store hydrogen but also contribute to the structural stiffness and load-carrying capability of the wing. Such multifunctional structures offer substantial opportunities for weight reduction and improved system efficiency, which are particularly valuable for aerospace applications.
Realisation of these advanced conformal pressure vessels requires materials and manufacturing technologies capable of producing lightweight, high-strength, and durable structures with complex geometries. The selected materials must exhibit excellent corrosion resistance, high damage tolerance, compatibility with advanced surface treatments and adhesive bonding processes, and, critically, low hydrogen permeability and leakage. Laminated fibre-reinforced polymer composites, together with advanced adhesive bonding technologies, satisfy many of these demanding requirements and therefore constitute the principal enabling technologies for next-generation hydrogen storage systems. Their exceptional design flexibility and multifunctional capabilities have motivated significant international research initiatives aimed at developing new classes of composite materials and manufacturing technologies for future hydrogen-powered vehicles [
93,
94,
95].
Cryogenic liquid hydrogen storage provides high volumetric energy density at 71 kg/m³ at −252.87 °C, with a mass storage efficiency of 14.2%, a gravimetric energy density of 5.57 kWh/kg, and a volumetric energy density of 1.68 kWh/L—translating to roughly 85% longer flight endurance compared to compressed gas systems of equivalent tank mass. The MetaVista multi-rotor platform developed in South Korea achieves flight endurance 727 minutes (12.1 hours, Guinness World Record, 2019) using a 6 L liquid hydrogen tank, establishing the current endurance record for commercial multi-rotor platforms. Ground handling complexity and infrastructure cost remain the primary barriers to large-scale commercialization [
16]. Cryo-compression raises mass storage efficiency to 7.38%, volumetric density to 0.045 kg H₂/L, and gravimetric energy density to 2.46 kWh/kg, but specialized infrastructure limits its UAV applicability at present.
Sodium Borohydride (NaBH₄) hydrolysis has been employed in UAV platforms developed by KARI and KAIST. The reaction
yields a volumetric specific energy of 739.1 Wh/L and gravimetric specific energy of 272.8 Wh/kg. However, the system-level penalty—including water supply, by-product collection vessels, and reaction chamber heating—adds 15–30% overhead mass compared to fuel weight alone, which narrows the net advantage over Type IV compressed storage for many tactical UAV classes [
97]. The approximately 25-minute start-up delay is an additional operational constraint.
Ammonia borane (NH₃BH₃) dehydrogenation at 120–180 °C offers hydrogen storage capacity up to 19.6 wt%, but slow reaction kinetics and gaseous impurity generation mean this approach remains at the research stage. Metal hydride storage (mass storage efficiency: 0.65%; gravimetric energy density: 0.26 kWh/kg) offers ambient-temperature stable storage, but low capacity and thermal management requirements limit practical deployment [
98].
Compared to the gas storage, liquid hydrogen storage operates at pressures below 1 MPa, which reduces the high costs related to with the compression of gas. However, the utilization of liquid hydrogen poses challenges such as the requirement for extremely low temperatures, and boil-off losses influenced by factors including thermal insulation quality, hydrogen volume, storage duration, environmental conditions, and tank geometry [
99]. Additionally, liquid hydrogen storage suffers from low energy efficiency, high overall costs, and significant energy consumption during the liquefaction process, known as the liquefaction energy penalty [
100].
The energy storage performance of the principal hydrogen storage methods can be compared simultaneously across both gravimetric and volumetric dimensions.
Figure 8 presents this two-axis comparison, allowing the relative trade-offs between mass efficiency and volume efficiency to be assessed directly for each storage technology class.
Figure 8 plots gravimetric energy density (Wh/kg, x-axis) against volumetric energy density (Wh/L, y-axis) for compressed gaseous hydrogen (Type III and IV cylinders at 350 and 700 bar), cryogenic liquid hydrogen, cryo-compression, sodium borohydride (NaBH₄) hydrolysis, and metal hydride storage. The diagram reveals a clear performance hierarchy: cryogenic liquid hydrogen achieves the highest volumetric density (approximately 1,680 Wh/L) owing to its storage density of 71 kg/m³ at −252.87 °C, while Type IV cylinders at 700 bar provide the most practical balance of gravimetric and volumetric performance within a structurally qualified envelope. Chemical hydride systems cluster at moderate-to-high volumetric densities but comparatively low gravimetric values, reflecting the system-level mass overhead of reaction chambers, water reservoirs, and by-product vessels. Metal hydrides occupy the lower-left quadrant, confirming their limited utility for mass-constrained UAV platforms. The Figure provides the quantitative basis for the technology selection guidance presented in the following paragraph and directly supports the design recommendations consolidated in
Table 6 for each mission profile category.
For UAV design, Type III–IV cylinders remain the preferred solution for operations with endurance below 6 hours and MTOW below 25 kg. Liquid hydrogen storage is increasingly favored for missions beyond six hours where infrastructure overhead is justified. Chemical hydrides occupy a middle ground for applications where ambient-temperature storage is operationally essential and start-up delay is acceptable.
Two fundamental equations govern hydrogen UAV endurance estimation. First, the gravimetric endurance model:
where E is endurance (h), mH₂ is usable hydrogen mass (kg), LHV = 33.3 kWh/kg is the lower heating value, ηsys is system efficiency (typically 0.40–0.55 for PEMFC + drivetrain), and Pcruise is cruise power demand (kW).
Second, the hybrid power balance equation governing instantaneous power split:
where PFC is the fuel cell output power, Pbat is battery power (positive during discharge, negative during charging), Pload is instantaneous propulsion demand, and Ploss represents converter and parasitic losses. During take-off, Pload typically reaches 2–5× cruise levels, requiring battery discharge to supplement fuel cell output [
17].