Supernumerary robotic limbs (SRLs) represent an emerging class of wearable robotic systems designed to augment, rather than replace, human motor capabilities. Unlike prostheses or exoskeletons, SRLs operate as independent kinematic agents that enable users to perform multi-limb tasks, reduce physical workload, and enhance operational efficiency in complex environments. This study presents a systematic review of SRL technologies, focusing on mechanical design configurations, sensing modalities, and control strategies, and their influence on key performance metrics such as payload capacity, positioning accuracy, and human–robot interaction efficiency. A structured literature review methodology was adopted following PRISMA guidelines, covering publications from 2010 to 2025 across major scientific databases. The analysis reveals fundamental trade-offs between degrees of freedom, weight, and payload capacity, where high-dexterity systems often impose increased ergonomic burden. Control strategies have evolved from direct teleoperation toward hybrid and shared-autonomy frameworks integrating vision, bio-signals, and machine learning, although challenges remain in achieving intuitive and low-latency interaction. Application domains span industrial manufacturing, construction, rehabilitation, and assistive daily activities, with growing interest in precision-constrained environments such as healthcare. Despite significant progress, limitations persist in actuator back-drivability, long-term wearability, and robust intention recognition under real-world conditions. This review synthesizes current advancements, identifies critical research gaps, and outlines future directions toward scalable, human-centric SRL systems capable of seamless integration into industrial and clinical workflows.