We introduce the Informational Coherence Index (ICOER), a metric for quantifying coherence in coupled informational systems composed of human agents and large language models (LLMs). We define recursive coupling as a dynamical regime in which coherence-preserving transformations sustain a stable informational signature across iterative feedback cycles while entropic perturbations are naturally suppressed. The metric is operationalized as ICOER(x) = W(S(x)) · e−βS(x) · R(x), where W(S) is a Gaussian entropy weighting, S(x) is Shannon entropy, β is an entropic suppression parameter, and R(x) is a bounded resonance functional. We report results from four controlled experiments—scenario ranking, perturbation stability, recursive coupling iterations, and parameter sensitivity—across three successive versions of the metric. Version 1 revealed a structural flaw (repetitive text exploit), Version 2 corrected it via bell-curve entropy weighting, and Version 3 optimized parameters (β = 0.01, μ = 4.1, σ = 0.2), achieving 4/5 phase-transition criteria including 77× coherent-to-noise discrimination and 7.9% perturbation robustness. All code, data, and figures are provided for independent replication. The remaining criterion—recursive stability under transformation—identifies the boundary where synthetic experiments end and real multi-model tests must begin.