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Determining the Size of an Undeformed Core in the Flow of an Unstructured Suspension from the Point of View of the Theory of Stability of Lipophobic Colloids

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09 September 2025

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10 September 2025

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Abstract
It has been shown for the first time that in the case of a pressure flow of a Newtonian fluid in a circular pipeline, the influence of forces of rheological origin, ion-electrostatic and Van der Waals nature on the radius of the undeformed flow core is described by a third-degree polynomial with respect to the thickness of the layer where the suspension structure is destroyed and its shear flow occurs. In this polynomial, the contribution of forces of rheological origin and the influence of the hydraulic size of the solid phase particles of the suspension are taken into account by a linear term. It has been proven that for the conditions of pressure flow of water-coal fuel, the influence of the hydraulic size of the solid phase particles of the suspension can be neglected in comparison with the influence of forces of rheological origin. The influence of ionic-electrostatic and Van der Waals forces is taken into account by quadratic and free terms. The quadratic term takes into account the influence of the distance between two adjacent particles in the suspension structure, and the free term is proportional to the total interaction energy of two spherical particles in a liquid. It has been proven that for conditions of pressure flow of water-coal fuel, the influence of the quadratic term of this polynomial can be neglected in comparison with the influence of its free term. Thus, for conditions of forced flow of water-coal fuel in a circular pipeline, it is proposed to determine the limiting value of the radius of the undeformed flow core as the root of a cubic equation containing cubic, linear and free terms. The free term of this polynomial at the points of equilibrium of ion-electrostatic and Van -der-Vaal nature is zero, and the limitation of the relative current radius of the undeformed flow core coincides with the dependence for determining the relative radius at which the structure of the suspension is still preserved during the flow of structured suspensions in a pipeline, exclusively according to rheological and hydraulic characteristics. At points of equilibrium between ionic-electrostatic and Van der Waals forces, the free term of this equation becomes either positive or negative. The results of the study of possible solutions to the cubic equation obtained using Cardan's method indicate that the sign of the free term does not affect the sign of the discriminant of the cubic equation. The sign of this discriminant depends on the ratio of the free term to its critical value, which depends on the relative radius of the undeformed flow core, determined by the ratio of the initial tangential stress to the tangential stress of hydraulic friction on the inner surface of the pipe. It is shown that with a positive discriminant, physically possible values of the radius of the undeformed flow core exist only in the case of a negative free term. When the free term of the cubic equation has positive values, they are physically impossible, since they imply the presence of a destruction boundary in the middle of the flow region where there is no deformation. With a negative discriminant, the sign of the free term affects the maximum value of the relative radius at which the structure of the suspension is still preserved when structured suspensions flow in a pipeline. In the case of a positive free term, the maximum value of the relative radius at which the structure of the suspension is still preserved during the flow of structured suspensions in a pipeline will exceed the relative radius of the undeformed flow core, which is determined by the rheological characteristics of structured suspensions. Conversely, in the case of a negative free member, the maximum value of the relative radius at which the structure of the suspension is still preserved during the flow of structured suspensions in a pipeline will be less than the relative radius of the undeformed flow core, which is determined by the rheological characteristics of structured suspensions.
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1. Introduction

The second half of the 20th century was characterised by the widespread use of pipeline transport. During this period, pipeline transport was used to transport homogeneous liquids, gases, polymer solutions, solid bulk materials, containers, air mixtures and hydro mixtures [1,2,3,4,5,6]. Of all these types of pipeline transport, the transportation of aqueous suspensions with solid particles smaller than 100 microns is considered the most complex and promising area. The peculiarities of the interaction of solid phase particles of the suspension with each other and with the liquid phase impose additional requirements on the calculation of hydraulic and technological parameters of this type of transport [7,8,9,10,11,12]. The experience of domestic and foreign specialists indicates the impossibility of solving such problems solely by methods of hydrodynamics of a heterogeneous medium. This scientific problem lies at the intersection of several sciences: hydrodynamics, rheology and physical chemistry [2,7,9,10]. Pipeline hydrotransport of structured suspensions (SS) has seen its greatest development in the technologies of manufacturing and transporting water-coal fuel (WCF) [2,3,5,6,8,9,13,14]. At the time when the idea of burning coal in the form of a structured water-coal suspension arose, well-developed methods of hydromechanics already existed for flows of polymer solutions of various concentrations in chemical technologies [15,16], or clay solutions in drilling and well cementing technologies [17,18,19]. This made it possible to quickly create the scientific basis for calculating the hydraulic parameters of pipeline systems for supplying WCS and to implement them in industry [1,2,3,4,5,6,7,8]. These methods are largely based on taking into account the rheological characteristics of WCS, and the operating modes of hydrotransport systems did not provide for stops and restarts. Experience in operating pipeline systems for supplying WCF has shown that most SS, unlike other types of hydraulic mixtures with solid particles larger than 100 microns, can exist in a stable state without destroying the structure with a uniform distribution of solid phase particles throughout the volume for several days. This means that flushing the system after shutdown and before start-up is not necessary. This raised new questions for researchers about the stability of WCF. That is why the further development of methods for calculating the parameters of pipeline transportation of WCF can be considered the application of the theory of stability of lyophobic colloids by Deryagin, Landau, Fairwayk, and Overbeck (DLFO), this made it possible to take into account the influence of gravitational and repulsive forces of an ionic-electrostatic and Van der Waals nature on flow regimes and hydrotranport parameters [2,7]. New prospects for the application of the scientific basis for calculating pipeline transport of WCF appeared at the turn of the 20th and 21st centuries, when the first technologies for pressure hydrotransport of mineral processing waste in the form of SS began to be developed and implemented [4,16], and later, technologies for the development of man-made deposits and deposits formed in artificial storage facilities began to be developed [6,20,21]. To this, we should add the latest approaches to enrichment waste storage facilities, which provide for their reprocessing and disposal, already being designed on the basis that SS will be used [1,4,8,14].
Thus, SS pipeline transport technologies have good prospects for use in the 21st century, but their widespread and effective implementation requires modernisation of the scientific basis for calculating the main parameters and operating modes, which will take into account not only rheological and hydraulic characteristics, but also forces of an ionic-electrostatic and Van der Waals nature.
The main difference between SS flow in a pipeline and Newtonian fluid flow is the presence of an undeformed flow core located along the flow axis. Traditionally, the ratio of the initial tangential stress to the tangential stress of hydraulic friction on the inner surface of the pipe is used to determine the radius of the undeformed flow core. However, some experimental studies of SS pressure flows in pipelines indicate that the values of the radius of the undeformed flow core obtained in this way cannot be applied at very small values and at values close to unity [15,22]. The reasons for this phenomenon are unknown. The methods limit these intervals, assuming that in the first case, turbulent flow has already been achieved, and in the second, laminar flow has already begun. There is a hypothesis that these effects are a manifestation of forces of an ion-electrostatic and Van der Waals nature.

2. Methods

According to the results obtained within the framework of the DLFO theory and adapted to the conditions of the pressure flow of the WCF, the destruction of the suspension structure, accompanied by an uneven distribution of solid phase particles throughout the suspension volume, occurs when the following condition is met [2,11,16,20,21]:
E C E T ,
where E C is the total energy of interaction between two spherical particles in a liquid; E T is the external energy of the flow directed at destroying the bond between the two particles.
Regarding the formula for determining the total interaction energy of two spherical particles in a liquid, most researchers propose the classical dependence of the DLFO theory [2,11,16,20,21]:
E C = 2 π r ε n ϕ δ 2 ln 1 + e y E y ;   E = A χ 24 π ε n ϕ δ 2 ;   y = χ h ,
where χ – reverse Debye radius, in most cases 1·108 m-1; E – parameter of energy interaction of solid phase particles SS; ε n – absolute dielectric permeability of liquid phase SS, 7.26·10–10 F/m; r – radius of solid phase particles SS, m; ϕ δ – potential of a diffuse particle of a double electric layer on the surface of solid phase particles SS, V; h – distance between solid phase particles SS, m; π – constant equal to 3.14; y – dimensionless distance between particles of the solid phase of SS, m; A – Hamaker constant, J.
While calculating the external energy of a flow aimed at destroying the connection between two particles, different researchers propose different approaches [2,3,7,10,11,12,14,16,21].
There is a well-known hypothesis that this energy is proportional to the difference in the velocities of the flows impinging on two adjacent particles [2,3]
E T = 0.5 α ρ f Δ U 3 S t ,
where α is the Coriolis coefficient; ρ f is the density of the liquid phase; Δ U is the difference in the velocities of the flows impinging on two adjacent particles in the coagulation structure, m/s; S is the cross-sectional area of the flow impinging on a single particle, m2; t is the duration of the flow, s.
The authors of dependence (3) do not explain why the energy of the flow is considered rather than the energy of the particles obtained from the flow. There is also no explanation of how to calculate the values of S and t. In general, the duration of the flow is characteristic of turbulent flows, where there are corresponding velocity pulsations along and across the flow. However, the destruction of the suspension structure occurs before the development of turbulence. The presence of the Coriolis coefficient in formula (3), which reflects the uneven distribution of the kinetic energy of the flow across the cross-sectional area, also requires additional justification.
Other authors believe that the external energy of the flow directed at destroying the connection between two particles is the kinetic energy of these particles, and propose the following dependence [5,7]
E T = 2 π 3 r 3 ρ s Δ u 2 ,
where Δ u is the difference in the velocities of the particles under consideration relative to each other, m/s; ρ s is the density of the solid phase.
Dependence (4) is very close to the difference in kinetic energies of interacting particles, provided that their sizes and densities are the same. However, in this case, instead of the square of the difference in the velocities of the particles under consideration relative to each other, it is necessary to use the difference in the squares of the velocities of these particles.
Within the hypothesis on which formula (4) is based, different results can be obtained for estimating the relative radius that defines the flow region where SS will not be destroyed, if different patterns of velocity distribution along the pipe radius are assumed [10,11,12,14,16,21]. There are known cases of using the logarithmic law [20,21], which does not correspond to the conditions in the layer between the inner surface of the pipeline and the undeformed flow core. A number of specialists who have studied the peculiarities of non-Newtonian fluid flow in a pipeline note that if we consider the destruction of the suspension structure during SS flow in a pipeline, the velocity distribution in the layer near the pipeline surface will correspond to the following dependence [10,11,16]
U s = R τ w 2 μ 1 s 2 2 1 s a ;   a = τ 0 τ w ;   τ w = Δ p R 2 L ;   s = r T R ,
where U – local flow velocity SS; R – pipe radius, m; r T – current radius value, m; s – relative current radius; τ w – tangential stress of hydraulic friction on the inner surface of the pipe, Pa; μ – dynamic viscosity coefficient of the liquid phase of the fluid, kg/m/s; a – relative radius of the undeformed flow core; τ 0 – initial tangential stress of the fluid flow, Pa; Δ p – pressure difference at the beginning and end of the pipeline, Pa; L – pipeline length, m.
Using dependence (5), the difference in the velocities of two particles of the solid phase SS, after neglecting the square of the relative distance between the particles of the solid phase SS, can be calculated using the following formula [16]
Δ U = η R τ w μ s η R τ 0 μ ;   η = h R ,
which made it possible to obtain a condition under which the structure of the suspension is destroyed when the SS flows in the pipeline [16]:
s > s * ;   s * = a ± μ η R τ w ln 1 + e y E y 36 ε n ϕ δ 2 r 2 ρ s ,
where s * is the maximum value of the relative radius at which the suspension structure is still preserved during the flow of SS in the pipeline; η is the relative distance between the particles of the solid phase of SS.
Note that the double sign in the second formula (7) appeared after taking the square root, i.e., it reflects a mathematical pattern, not a physical one. In addition, note that under the first root on the right side of the second formula (7) is the relative value of the total interaction energy of two spherical particles in a liquid, the first formula (2). This value is zero at equilibrium points, but becomes positive or negative in other cases. At the same time, if we consider the second formula (7) at equilibrium points, its second term is zero, and it coincides with the dependence for determining the relative radius at which the structure of the suspension is still preserved during SS flow in the pipeline, exclusively according to rheological and hydraulic characteristics, the second formula from (5).
In our opinion, if we consider that the external energy of the flow directed at destroying the connection between two particles is the kinetic energy of these particles, then it must be equal to the difference in the kinetic energies of the adjacent particles. That is, with the same sizes and densities of these particles, this difference in kinetic energies will be proportional to the difference in the squares of the velocities at which each of the compatible particles will move under the action of the flow:
E T = 2 3 π r ρ s V 1 2 V 2 2 ,
where V 1 is the velocity of the particle with the smaller current radius, m/s; V 2 is the velocity of the particle with the larger current radius, m/s.
The results of fundamental research on the flow of hydro-mixtures through pipelines, carried out by domestic authors [1,4,10,11,12,13,14,16,20,21], indicate that the velocity of a solid particle in a hydro mixture flow is determined by the difference between the velocity of the liquid phase and the hydraulic size of this particle. Based on this experimental fact and using the first formula from (5), after the appropriate transformations, we write the following dependencies to calculate the velocities of each of the adjacent particles:
V 1 = R τ w 2 μ 1 a 2 s a 2 w ;   V 2 = V 1 R τ w μ η s a + η 2 ,
where w – hydraulic particle size of the solid phase, m/s.
Neglecting in the second formula (9) the quadratic term with the relative distance between the particles of the solid phase SS
V 2 V 1 R τ w μ η s a ,
The difference between the squares of the velocities in dependence (8) can be easily written as follows
V 1 2 V 2 2 = R τ w μ 2 2 η 1 a 2 b s a η 2 s a 2 s a 3 ;   b = μ w R τ w ,
where b – dimensionless hydraulic particle size of the solid phase, m/s.
Considering jointly the first formula of the last two, (8), the first formula of (2) and inequality (1), and taking into account that
After the appropriate transformations, we obtain a condition under which the structure of the suspension is destroyed when the SS flows in the pipeline, in the form of the following inequality
s a 3 + y 2 χ R s a 2 1 a 2 b s a + a 2 B 0 ; B = 3 2 ε n ϕ δ 2 ρ s R μ τ 0 2 χ y ln 1 + e y E y ,
where B is the lyophobicity parameter, which takes into account the influence of gravitational and repulsive forces of an ionic-electrostatic and Van der Waals nature.
The results of the analysis of the orders of magnitude on the left side (10) indicate that the second term of this polynomial can be neglected in comparison with the others, and the dimensionless hydraulic particle size of the solid phase, in the case of WCF and most mineral processing wastes, is several orders of magnitude smaller than the square of the dimensionless thickness of the deformed part of the flow. Based on this, inequality (10) can be rewritten as follows:
s a 3 1 a 2 s a + a 2 B 0 .
If we consider condition (7) at equilibrium points, when 0 B, we obtain a restriction on the relative current radius
a s 1 ,
which coincides with the dependence for determining the relative radius at which the suspension structure is still preserved during SS flow in the pipeline, exclusively based on rheological and hydraulic characteristics, the second formula from (5).
Note that in inequality (11), the lyophobicity parameter contains the relative value of the total interaction energy of two spherical particles in a liquid, the first of the formulas (2), but not under the square root, as is the case in formula (7). That is, if we consider (11) not at equilibrium points, then the value of the lyophobicity parameter becomes either positive or negative, and the form of inequality (11) changes. However, the sign of the lyophobicity parameter does not affect the sign of the discriminant of the corresponding cubic equation, which must be solved to determine the intervals of inequality (11). The sign of this discriminant depends on the ratio of the lyophobicity parameter and the relative radius of the undeformed flow core. This discriminant will be positive if the inequality
B 2 4 27 1 a 3 a 4 ,
and the cubic equation (11) has one real root, which is determined by the formula
z = a 2 2 B 3 1 1 4 27 1 a 3 a 4 B 2 3 + 1 + 1 4 27 1 a 3 a 4 B 2 3 .
With a positive discriminant, regardless of the sign of the lyophobicity parameter, we obtain the following formula for calculating the maximum value of the relative radius at which the suspension structure is still preserved during SS flow in the pipeline:
s * = a z ,
where z is the real root of equation (11), determined by formula (12).
The effect of the lyophobicity parameter sign is a restriction imposed by s * on the value of the relative current radius. Thus, in the case of a positive lyophobicity parameter, B > 0 , the relative current radius is limited from above:
s < s * ,
and when negative, B < 0 , from below:
s > s * .
It is clear that condition (14) is physically impossible, since it presupposes the existence of a destruction boundary in the middle of the flow region where there is no deformation.
With a negative discriminant, when the following inequality holds
B 2 < 4 27 1 a 3 a 4 .
Regardless of the sign of the lyophobicity parameter, there are three valid roots of equation (11):
X = 2 3 1 a cos α 3 ;   Y = 2 3 1 a cos α 3 + π 3 ;
Z = 2 3 1 a cos α 3 π 3 ;   cos α = 27 a 2 B 2 1 a 3 ,
and the intervals of existence of the solution of inequality (11) will be:
s s * ;   s s s ;   s * = a Z .
The influence of the lyophobicity parameter sign lies in the values of the second interval limits. Thus, in the case of a positive lyophobicity parameter, B > 0 , the values s and s are calculated as the sums of the relative radius of the undeformed flow core and the roots of equation (11):
s = a + Y ;   s = a + X ,
and in the case of a negative parameter, B < 0 , – as differences:
s = a Y ;   s = a X .
The first constraint from (16), as well as (14), is physically impossible, i.e., with a negative discriminant of equation (11), only the second constraint from (16) needs to be considered. Formulas (17) and (18) show that in the case of a positive lyophobicity parameter, B > 0 , the maximum value of the relative radius at which the suspension structure is still preserved during SS flow in the pipeline will exceed the relative radius of the undeformed flow core, which is determined by the rheological characteristics of SS. Conversely, for a negative lyophobicity parameter, B < 0 , the maximum value of the relative radius at which the suspension structure is still preserved during the flow of SS in the pipeline will be less than the relative radius of the undeformed flow core, which is determined by the rheological characteristics of SS.

3. Results and Discussion

Analysis of formulas (11) – (18) indicates that the value of the lyophobicity parameter can be determined as a proportional function of the relative radius of the undeformed flow core
B = k 2 3 1 a a 2 1 a 3 ,
which allows, in the case of a positive discriminant, to determine the solution (12) in the following form
z = 1 a a 2 3 E k ;   E = k 3 3 1 1 1 k 2 3 + 1 + 1 1 k 2 3 ,
where E is the lyophobicity function (Figure 1); k is the proportionality coefficient, k > 1 .
Calculations using the first formula (20) (Figure 2) show that the values of the real root of equation (11), determined by formula (12), may exceed the corresponding value of the relative radius of the undeformed flow core, which makes the values negative s * (Figure 3).
It is impossible to analytically determine the permissible values of the proportionality coefficient and the relative radius of the undeformed flow core that satisfy the positive values of s * , taking into account the nonlinear nature of the dependence (20). The results of numerical processing of the second formula from (20) show that the dependence of the lyophobicity function on the proportionality coefficient with an accuracy acceptable for engineering calculations R 2 = 0.997 , can be approximated by a step function:
E = 0.6703 k 0.1932 .
Considering formulas (21), (20) and (13) together with the requirement of a positive value s * , we obtained the following restrictions
k k * ;   a a * ;   k * = 7.93 a 3 1 a 5.18 ;   a * = 0.173 k 0.4 ,
where k * is the permissible value of the proportionality coefficient; a * is the permissible value of the relative radius of the undeformed flow core.
By analogy with the case of a positive discriminant, in the case of a negative discriminant, the value of the lyophobicity parameter can be determined using (19), but with a different interval of existence
1 < k < 1 ,
which allows calculating the roots of equation (11) (Figure 4) and the corresponding limits at which the suspension structure is destroyed during SS flow in the pipeline (Figure 5), since it becomes possible to calculate the cosine of the characteristic angle
cos α = σ 1 a 3 .
Figure 5 shows that the conditions of physical reality correspond to the second interval (16) (Figure 6), the width of which is calculated using the formula (Figure 7)
Δ = 1 a sin α 3 + cos α 3 3 ,
where ∆ is the width of the interval relative to the current radius where the suspension structure is destroyed during SS flow in the pipeline.
Note that when calculating using formulas (16) – (22), the value of the proportionality coefficient k is determined by the following formula
k = 27 a 2 4 1 a 3 2 ε n ϕ δ 2 ρ s R μ τ 0 2 χ y ln 1 + e y E y .
Taking into account various restrictions on the proportionality coefficient that exist for different values of the discriminant of equation (11), relation (23) allows to limit the total interaction energy of two adjacent spherical particles in a liquid.
F y < ln 1 + e y E y ; F y < ln 1 + e y E y < F y ;   F = 4 1 a 3 2 27 a 2 ε n ϕ δ 2 ρ s χ R τ 0 μ 2 ,
where F is the external energy parameter of the flow.

4. Conclusions

It has been shown for the first time that in the case of a pressure flow of a Newtonian fluid in a circular pipeline, the influence of forces of rheological origin, ion-electrostatic and Van der Waals nature on the radius of the undeformed flow core is described by a third-degree polynomial with respect to the thickness of the layer where the destruction of the suspension structure and its shear flow occur. In this polynomial, the contribution of forces of rheological origin and the influence of the hydraulic size of the solid phase particles of the suspension are taken into account by a linear term. It has been proven that for conditions of pressure flow of the WCF, the influence of the hydraulic size of the solid phase particles of the suspension can be neglected in comparison with the influence of forces of rheological origin. The influence of ion-electrostatic and Van der Waals forces is taken into account by quadratic and free terms. The quadratic term takes into account the influence of the distance between two adjacent particles in the suspension structure, and the free term is proportional to the total interaction energy of two spherical particles in the liquid. It has been proven that for the conditions of pressure flow of WCF, the influence of the quadratic term of this polynomial can be neglected in comparison with the influence of its free term. Thus, for conditions of pressure flow of WCF in a circular pipeline, it is proposed to determine the limiting value of the radius of the undeformed flow core as the root of a cubic equation containing cubic, linear and free terms. The free member of this polynomial at the equilibrium points of ion- electrostatic and Van der Waals forces is equal to zero, and the limitation of the relative current radius of the undeformed flow core coincides with the dependence for determining the relative radius at which the suspension structure is still preserved during SS flow in the pipeline, exclusively based on rheological and hydraulic characteristics. At points of equilibrium between ionic-electrostatic and Van der Waals forces, the free term of this equation becomes either positive or negative. The results of the study of possible solutions to the cubic equation obtained using Cardan’s method indicate that the sign of the free term does not affect the sign of the discriminant of the cubic equation. The sign of this discriminant depends on the ratio of the free term to its critical value, which depends on the relative radius of the undeformed flow core, determined by the ratio of the initial tangential stress to the tangential stress of hydraulic friction on the inner surface of the pipe.
It is shown that with a positive discriminant, physically possible values of the radius of the undeformed flow core exist only in the case of a negative free term. With positive values of the free term of the cubic equation, they are physically impossible, since they imply the presence of a destruction boundary in the middle of the flow region where there is no deformation. With a negative discriminant, the sign of the free term affects the maximum value of the relative radius at which the suspension structure is still preserved during SS flow in the pipeline. In the case of a positive free term, the maximum value of the relative radius at which the suspension structure is still preserved during SS flow in the pipeline will exceed the relative radius of the undeformed flow core, which is determined by the rheological characteristics of the SS. Conversely, in the case of a negative free term, the maximum value of the relative radius at which the structure of the suspension is still preserved during the flow of SS in the pipeline will be less than the relative radius of the undeformed flow core, which is determined by the rheological characteristics of SS.

Author Contributions

Conceptualization, E.S., O.K. and A.Z.; methodology, E.S.; validation, O.K.; formal analysis, E.S. and O.K.; investigation, O.K.; resources, E.S. and A.Z.; data curation, E.S.; writing—original draft preparation, E.S. and O.K.; writing—review and editing, A.Z.; visualization, E.S.; supervision, O.K.; project administration, O.K. and A.Z.; funding acquisition, A.Z. All authors have read and agreed to the published version of the manuscript.

Data Availability Statement

The data supporting the findings of this study are contained within the article. No additional datasets were generated or analysed during the current study. All theoretical derivations, analytical models, and numerical evaluations are based on established literature and are fully described in the text. Researchers seeking further clarification on the methodology or equations used are encouraged to consult the cited references.

Acknowledgments

This work was supported by projects “Integrated modeling for robust management of food-energy-water-social-environmental (FEWSE) nexus security and sustainable development” (IIASA-NASU, 22-501 (R-45-T)), “Comprehensive analysis of robust preventive and adaptive measures of food, energy, water and social management in the context of systemic risks and consequences of COVID-19” (0122U000552, 2022–2026), “Development of the structure and ensuring the functioning of self-sufficient distributed generation” (0125U001572, 2025-2026), which are financed by National Academy of Science of Ukraine.

Conflicts of Interest

The authors declare no conflicts of interest.

Abbreviations

The following abbreviations are used in this manuscript:
DLFO Deryagin–Landau–Fairwayk–Overbeck
SS Structured suspension
WCF Water-coal fuel

References

  1. Semenenko, E.; Kirichko, S. Grounds of Parameters of High-Concentrated Pulps Storage Technologies. In Theoretical and Practical Solutions of Mineral Resources Mining; Pivnyak, Bondarenco, Kovalevska, Eds.; Taylor & Francis Group: London, UK, 2015; pp. 373–377. [Google Scholar]
  2. Krut’, O.A. Water-Coal Fuel; Naukova Dumka: Kyiv, Ukraine, 2002; 172p. [Google Scholar]
  3. Svitlyi, Y.H.; Krut’, O.A. Hydraulic Transport of Solid Materials; Skhidnyi Vydavnychyi Dim: Donetsk, Ukraine, 2010; 268p. [Google Scholar]
  4. Blyuss, B.; Semenenko, Y.V.; Medvedieva, O.; Kyrychko, S.; Karatayev, A. Parameters Determination of Hydromechanization Technologies for the Dumps Development as Technogenic Deposits. Min. Miner. Depos. 2020, 14, 51–61. [Google Scholar] [CrossRef]
  5. Svitlyi, Y.H.; Biletskyi, V.S. Hydraulic Transport; Skhidnyi Vydavnychyi Dim: Donetsk, Ukraine, 2009; 436p. [Google Scholar]
  6. Kyrychko, S.M. Justification of Parameters of Hydromechanization Processes for Mining Operations Using High-Concentration Hydro-Mixtures; Candidate of Technical Sciences Thesis, Spec. 05.15.09; Institute of Geotechnical Mechanics NAS of Ukraine: Dnipro, Ukraine, 2016; 175p. [Google Scholar]
  7. Biletskyi, V.S.; Krut’, O.A.; Serhiev, P.V. Water-Coal Suspension from the Perspective of the Theory of Aggregate Stability of Lyophobic Dispersed Systems. Rep. Natl. Acad. Sci. Ukraine 2013, 5, 95–103. [Google Scholar]
  8. Shvornikova, H.M. Reducing Energy Consumption for Water-Coal Fuel Transport by Improving Processes and Operation Modes of Hydrotechnical Systems; Candidate of Technical Sciences Thesis, Spec. 05.22.12; Taras Shevchenko National University of Luhansk: Luhansk, Ukraine, 2010; 191p. [Google Scholar]
  9. Biletskyi, V.S.; Krut’, O.A.; Vlasov, Y.F. Rheological Characteristics of Water-Coal Suspensions Depending on Raw Coal Quality. Bull. Kryvyi Rih Techn. Univ. 2006, (11), 49–55. [Google Scholar]
  10. Semenenko, Y.V.; Slobodiannykova, I.L.; Tepla, T.D.; Tatarko, L.H. Determination of the Pressure Flow Parameters of a Structured Suspension. Geotech. Mech. 2023, 167, 129–141. [Google Scholar] [CrossRef]
  11. Semenenko, Y.V.; Medvedieva, O.O.; Tatarko, L.G.; Khamynych, O.V.; Yeluzakh, M. Influence of the Properties of Solid Particles Added to a Structured Suspension on Its Dynamic Sedimentation Stability. Geotech. Mech. 2022, 163, 96–107. [Google Scholar] [CrossRef]
  12. Phillips, R.J. Structural instability in the sedimentation of particulate suspensions through viscoelastic fluids. J. Non-Newtonian Fluid Mech. 2010, 165, 479–488. [Google Scholar] [CrossRef]
  13. Papayani, F.A.; Switly, Y.G. Utilization of Coal-Water Fuel in Heat Power Industry and by Public Utilities of Ukraine. In Coal Utilization & Fuel Systems: Proceedings of the 20th International Technical Conference; March 1995; Clearwater, FL, USA, 1995; pp. 193–202.
  14. Semenenko, Y.V.; Tepla, T.D.; Medianyk, V.Yu.; Skosyrev, V.H.; Babets, D.V. Determination of the Non-Deformable Core Radius of Flow in Structured Suspension Pipeline Using the Theory of Stability of Lyophobic Colloids. Geotech. Mech. 2023, 165, 84–96. [Google Scholar] [CrossRef]
  15. Yakhno, O.M.; Zhelyak, I.V. Hydraulics of Non-Newtonian Fluids; Vyscha Shkola: Kyiv, Ukraine, 1995; 199p. [Google Scholar]
  16. Angardi, V.; Ettehadi, A.; Yücel, Ö. Critical review of emulsion stability and characterization techniques in oil processing. J. Energy Resour. Technol. 2022, 144, 040801. [Google Scholar] [CrossRef]
  17. Mysliuk, M.A.; Bohoslavets, V.V. Hydroaeromechanics in Drilling: Methodical Guidelines; Ivano-Frankivsk National Technical University of Oil and Gas: Ivano-Frankivsk, Ukraine, 2017; 31p. [Google Scholar]
  18. Dudlya, M.A. Drilling Fluids; 3rd ed.; National Mining University: Dnipro, Ukraine, 2011; 542 p.
  19. Petunin, O.I.; Zelenskyy, A.A. High-Quality Drilling Fluids—The Key to Successful Construction of Oil and Gas Wells [Special Issue]. Burinnia 2010, (X), 9–15. [Google Scholar]
  20. Semenenko, E.V.; Demchenko, T.D.; Ryzhova, S.A. Investigation of Dynamic Sedimentation Stability of Structured Suspensions under Turbulent Pulsations. Geotechnical Mech. 2016, 130, 115–124. [Google Scholar]
  21. Semenenko, Y.V.; Slobodiannykova, I.L.; Medianyk, V.Yu.; Kyrychko, S.M.; Tepla, T.D. Technologies for the Removal of Coal Technogenic Deposits in the Form of Highly Concentrated Hydro-Mixtures. Geotech. Mech. 2022, 163, 46–60. [Google Scholar] [CrossRef]
  22. Kurganov, A.M. (Ed.) Hydraulic Calculations of Water Supply and Sewerage Systems: Handbook, 3rd ed.; revised and expanded; Stroizdat: Leningrad, USSR, 1986; 440p. [Google Scholar]
Figure 1. Dependence of the lyophobicity function on the proportionality coefficient.
Figure 1. Dependence of the lyophobicity function on the proportionality coefficient.
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Figure 2. Dependence of the value z on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
Figure 2. Dependence of the value z on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
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Figure 3. Dependence of the value s * on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
Figure 3. Dependence of the value s * on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
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Figure 4. Dependence of the roots of equation (11), with a negative discriminant, on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
Figure 4. Dependence of the roots of equation (11), with a negative discriminant, on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
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Figure 5. Dependence of the limits of intervals in which the suspension structure is destroyed during SS flow in a pipeline on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
Figure 5. Dependence of the limits of intervals in which the suspension structure is destroyed during SS flow in a pipeline on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
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Figure 6. Dependence of the limits of intervals in which the suspension structure is destroyed during SS flow in a pipeline on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
Figure 6. Dependence of the limits of intervals in which the suspension structure is destroyed during SS flow in a pipeline on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
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Figure 7. Dependence of the width of the interval in which the suspension structure is destroyed during SS flow in a pipeline on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
Figure 7. Dependence of the width of the interval in which the suspension structure is destroyed during SS flow in a pipeline on the proportionality coefficient for different values of the relative radius of the undeformed flow core.
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