Krause, T.; Nusko, D.; Pitta Bauermann, L.; Vetter, M.; Schäfer, M.; Holly, C. Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review. Energies2024, 17, 1566.
Krause, T.; Nusko, D.; Pitta Bauermann, L.; Vetter, M.; Schäfer, M.; Holly, C. Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review. Energies 2024, 17, 1566.
Krause, T.; Nusko, D.; Pitta Bauermann, L.; Vetter, M.; Schäfer, M.; Holly, C. Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review. Energies2024, 17, 1566.
Krause, T.; Nusko, D.; Pitta Bauermann, L.; Vetter, M.; Schäfer, M.; Holly, C. Methods for Quantifying Expansion in Lithium-Ion Battery Cells Resulting from Cycling: A Review. Energies 2024, 17, 1566.
Abstract
Significant efforts are being made across academia and industry to better characterize lithium-ion battery cells as reliance on the technology for applications ranging from green energy storage to electric mobility increases. The measurement of short-term and long-term volume expansion in lithium-ion battery cells is relevant for several reasons. For instance, it provides information about the quality and homogeneity of battery cells during charge and discharge cycles, as well as aging over it’s lifetime. The expansion measurements are useful for the evaluation of new materials and the improvement of end-of-line quality tests during cell production. These measurements may also indicate the safety of battery cells by aiding in predicting state of charge and state of health over the lifetime of the cell. Expansion measurements can also assess inhomogeneities on the electrodes and defects such as gas accumulation and lithium plating. In this review, we first establish the known mechanisms through which short term and long term volume expansion in lithium-ion battery cells occurs. We then explore the current state-of-the-art for both contact and non-contact measurements of volume expansion. This review compiles existing literature to outline the various options available to researchers aiming to make ex situ volume expansion measurements by doing post mortem analyses on individual components and in operando measurements on entire battery cells. Finally, we discuss the different considerations when selecting an appropriate measurement technique. The selection of the optimal method for measuring battery cell expansion depends on the objective of the characterization, duration, required resolution, and repeatability of results. Costs and required space for the measurement equipment are also considered.
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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