Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Thermodynamic Insights into Symmetry-Breaking: Exploring Energy Dissipation across Diverse Scales

Version 1 : Received: 31 January 2024 / Approved: 15 February 2024 / Online: 16 February 2024 (02:27:36 CET)

A peer-reviewed article of this Preprint also exists.

Arango-Restrepo, A.; Rubi, J.M. Thermodynamic Insights into Symmetry Breaking: Exploring Energy Dissipation across Diverse Scales. Entropy 2024, 26, 231. Arango-Restrepo, A.; Rubi, J.M. Thermodynamic Insights into Symmetry Breaking: Exploring Energy Dissipation across Diverse Scales. Entropy 2024, 26, 231.

Abstract

Symmetry-breaking is a phenomenon that is observed in various contexts, from the early universe to complex organisms, and is considered a key puzzle in understanding the emergence of life. The presence of enantiomeric amino acids and proteins highlights its critical role. However, the origin of symmetry-breaking has yet to be comprehensively explained, particularly from an energetic standpoint. This article explores a novel approach by considering energy dissipation, specifically lost free energy, as a crucial factor in elucidating symmetry-breaking. Through a thorough thermodynamic analysis applicable to enantiomeric systems at various scales, from elementary particles to aggregated matter like crystals, we present experimental findings that establish a direct correlation between non-equilibrium free energy and energy dissipation during formation processes. Results emphasize the pivotal role of energy dissipation not only as an outcome but as the trigger for symmetry-breaking. This insight suggests that understanding the origins of complex systems, from cells to living beings and the universe itself, requires a lens focused on non-equilibrium processes, ultimately facilitating the formation of non-racemic systems.

Keywords

Energy Dissipation; Entropy production; Matter aggregation; Mesostructures; Self-assembly; Self-organization; Symmetry-breaking

Subject

Physical Sciences, Thermodynamics

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