Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Nutritional and Phytochemical Profiles of Wild Adlay (Coix lacryma-jobi L.) Accessions by GCFID, FTIR, and Spectrophotometer

Version 1 : Received: 13 February 2024 / Approved: 13 February 2024 / Online: 13 February 2024 (07:31:30 CET)

How to cite: Ahmad, R.; Mueed, A.; Liaquat, M.; Sammi, S.; Jahangir, M.; Mumtaz, A.; Khan, I.; Al-Anazi, K.M.; Farah, M.A.; Ali, A. Nutritional and Phytochemical Profiles of Wild Adlay (Coix lacryma-jobi L.) Accessions by GCFID, FTIR, and Spectrophotometer. Preprints 2024, 2024020722. https://doi.org/10.20944/preprints202402.0722.v1 Ahmad, R.; Mueed, A.; Liaquat, M.; Sammi, S.; Jahangir, M.; Mumtaz, A.; Khan, I.; Al-Anazi, K.M.; Farah, M.A.; Ali, A. Nutritional and Phytochemical Profiles of Wild Adlay (Coix lacryma-jobi L.) Accessions by GCFID, FTIR, and Spectrophotometer. Preprints 2024, 2024020722. https://doi.org/10.20944/preprints202402.0722.v1

Abstract

Cultivated adlay or Job’s tear (Coix lacryma-jobi L.) is an important food crop having numerous therapeutic and nutraceutical health benefits. Our study aimed to determine nutrients, minerals, fatty acid composition, and functional groups of seven wild Adlay accessions (brown, black, yellow, grey, green, off-white, and purple) to find out their scope as cereal crops using simple, rapid, and modern analytical techniques. Results revealed variations among bulk densities, specific densities, percent empty spaces, and corresponding grain counts per 10g of sample are valuable characteristics in distinguishing the accessions. Contents of fat, protein, ash, and fibre were found to be comparable to cultivated Adlay. Brown adlay was measured with the highest protein, fat, and fibre contents, 15.82%, 4.76% and 2.37%, respectively. Phosphorus, potassium, calcium, and sodium ranged 0.3% - 2.2%, whereas boron, iron, copper, zinc, and manganese were in the range 1.6mg/kg - 20.8mg/kg. Wild adlay triglyceride composition constituted of polyunsaturated fatty acids as primary fraction followed by olein and palmitic acid as prominent fatty acids. Distinguishing functional groups expressed infra-red frequencies in narrow bands and fingerprint region of proteins associated with out-of-plane region evident structural differences among adlay accessions. Frequency of functional groups in seven accessions indicated black genotype promising for varietal development.

Keywords

Adlay; functional groups; physicochemical; triglyceride; GCFID; FTIR

Subject

Chemistry and Materials Science, Analytical Chemistry

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