Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Plasma Treatment of the Large-Area Polymer Substrates for the Enhanced Adhesion of UV-Digital Printing

Version 1 : Received: 2 February 2024 / Approved: 2 February 2024 / Online: 2 February 2024 (16:12:11 CET)

A peer-reviewed article of this Preprint also exists.

Fleischer, M.; Kelar Tučeková, Z.; Galmiz, O.; Baťková, E.; Plšek, T.; Kolářová, T.; Kováčik, D.; Kelar, J. Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing. Nanomaterials 2024, 14, 426. Fleischer, M.; Kelar Tučeková, Z.; Galmiz, O.; Baťková, E.; Plšek, T.; Kolářová, T.; Kováčik, D.; Kelar, J. Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing. Nanomaterials 2024, 14, 426.

Abstract

UV-digital printing belongs to the commonly used method for custom large-area substrate decoration. Despite low surface energy and adhesion, transparent polymer materials, such as polymethylmethacrylate (PMMA) and polycarbonate (PC), represent an ideal substrate for such purposes. The diffuse coplanar surface barrier discharge (DCSBD) in a novel compact configuration was used for substrate activation to improve ink adhesion to the polymer surface. This industrially applicable version of DCSBD was prepared, tested, and successfully implemented for the UV-digital printing process. Furthermore, wettability and surface free energy measurement, X-ray photoelectron spectroscopy, atomic force and scanning electron microscopy evaluated the surface chemistry and morphology changes. The changes in adhesion of the surface and of ink were analyzed by a peel-force and a crosscut test, respectively. A short plasma treatment (1-5 s) enhanced the substrate's properties of PMMA and PC while providing the pre-treatment suitable for further in-line UV-digital printing. Furthermore, we did not observe damage or significant change of roughness affecting the substrate's initial transparency.

Keywords

UV-digital printing; transparent polymers; low-temperature plasma; surface functionalization; ink adhesion.

Subject

Chemistry and Materials Science, Polymers and Plastics

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