Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Blended Calcium Sulfoaluminate Cements Based on Thermally Treated Reservoir Sediments

Version 1 : Received: 10 January 2024 / Approved: 11 January 2024 / Online: 11 January 2024 (08:04:20 CET)

A peer-reviewed article of this Preprint also exists.

Telesca, A.; Marroccoli, M. Fabrication and Properties of Blended Calcium Sulfoaluminate Cements Based on Thermally Treated Reservoir Sediments. Appl. Sci. 2024, 14, 1359. Telesca, A.; Marroccoli, M. Fabrication and Properties of Blended Calcium Sulfoaluminate Cements Based on Thermally Treated Reservoir Sediments. Appl. Sci. 2024, 14, 1359.

Abstract

In 2021 the total world cement production was estimated at 4.1 billion tonnes and the annual CO2 emissions from cement plants reached almost 2.8 billion metric tonnes. In the last years many ef-forts have been made for manufacturing low-CO2 cements. In this regard, a great attention has been paid towards calcium sulfoaluminate (CSA) cements for both their peculiar technical prop-erties and the environmentally friendly features mainly related to their manufacturing process. Moreover, the use of blended cements composed by CSA binders and supplementary cementitious materials (SCMs) could represents a powerful tool for both reducing the CO2 footprint and pro-ducing more durable environmentally friendly materials. In this paper, the possibility of using reservoir sediments (RS), calcined at 830°C, as SCMs in blended-CSA cements was investigated. Four binders were submitted to hydration and physico-mechanical tests for curing periods com-prised in the interval 4 hours-56 days. X-ray fluorescence, X-ray diffraction and differential thermal–thermogravimetric analyses were employed as main characterization techniques. It was found that thermally treated RS are very interesting inasmuch as their utilization allows a CSA clinker dilution, thus implying both a decrease of CO2 emissions and a reduction of costs related to CSA cement production.

Keywords

calcium sulfoaluminate cements; thermally treated reservoir sediments; supplementary cementitious materials; hydration; expansion; mechanical strength

Subject

Chemistry and Materials Science, Materials Science and Technology

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