Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

A New Approach for Bioremediation of Olive Mill Wastewaters: Combi-Nation of Straw Filtration and Nanofiltration

Version 1 : Received: 9 January 2024 / Approved: 9 January 2024 / Online: 9 January 2024 (10:44:49 CET)

A peer-reviewed article of this Preprint also exists.

Chidichimo, F.; Basile, M.R.; Conidi, C.; De Filpo, G.; Morelli, R.; Cassano, A. A New Approach for Bioremediation of Olive Mill Wastewaters: Combination of Straw Filtration and Nanofiltration. Membranes 2024, 14, 38. Chidichimo, F.; Basile, M.R.; Conidi, C.; De Filpo, G.; Morelli, R.; Cassano, A. A New Approach for Bioremediation of Olive Mill Wastewaters: Combination of Straw Filtration and Nanofiltration. Membranes 2024, 14, 38.

Abstract

A combination of straw filtration and nanofiltration was investigated for the first time as a sus-tainable approach aimed at valorizing olive mills wastewaters (OMWs) within a circular economy strategy. Ground straw filters with different granulometry (120, 250 and 500 m) were tested in the first step to clarify the raw wastewater. The 500m filter offered the best performance due to a lower exposed surface of the filtering fibers and a shorter filtering time allowing to reduce about 70% of the COD of the raw wastewater. Three different commercial membranes in flat-sheet con-figuration with molecular weight cut-off (MWCO) in the range 150-500 Da were tested to frac-tionate the clarified wastewater according to a dead-end configuration. Among the investigated membranes the NFA-12A membrane exhibited the highest productivity in selected operating conditions (steady-state values of 11.4 L/m2h at 20 bar and 24 ± 2 °C). In addition, flux decays for this membrane resulted lower than the other two tested membranes indicating a lower propensity to fouling phenomena. Higher rejections towards total polyphenols and TAA (76.6% and 73.2%, respectively) were also observed for this membrane. Flavanols and hydroxycinnamic acids were retained for more than 99%. The combination of straw filtration and NF with NFA-12A membrane allowed to reduce the COD of raw OMWs up to 97.6%. The retentate fraction of this membrane exhibited a TAA of 18.9 ± 0.7 mM Trolox supporting its propensity for the development of inno-vative formulations of interest in food and nutraceutical applications.

Keywords

Olive mill wastewaters; straw filtration; nanofiltration; phenolic compounds

Subject

Environmental and Earth Sciences, Waste Management and Disposal

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