Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Recent Advances in Solid-State Modification for Thermoplastic Polymers: A Comprehensive Review

Version 1 : Received: 30 December 2023 / Approved: 3 January 2024 / Online: 4 January 2024 (01:24:03 CET)

A peer-reviewed article of this Preprint also exists.

Perez Bravo, J.J.; Gerbehaye, C.; Raquez, J.-M.; Mincheva, R. Recent Advances in Solid-State Modification for Thermoplastic Polymers: A Comprehensive Review. Molecules 2024, 29, 667. Perez Bravo, J.J.; Gerbehaye, C.; Raquez, J.-M.; Mincheva, R. Recent Advances in Solid-State Modification for Thermoplastic Polymers: A Comprehensive Review. Molecules 2024, 29, 667.

Abstract

This review provides an extensive overview of the developments in the field of polymer science, focusing on the solid-state modification (SSM) of thermoplastic materials. The background of the study places thermoplastics within the context of their increased use over the past century, highlighting their versatility in various applications and the associated environmental and health concerns due to certain additives. The methods section delves into the specifics of SSM, a technique that involves the incorporation of monomers or oligomers into the amorphous phase of polymers through multiple exchange reactions, distinguishing it from traditional melt polymer modification methods. The results section outlines the unique aspects of SSM and its increasing recognition for its potential to enhance material performance in areas such as catalysts and composites. It also discusses the application of SSM in modifying different thermoplastic polymers, highlighting various studies demonstrating the method's effectiveness in altering polymer properties. Finally, this work emphasizes SSM's importance in environmental sustainability and its potential in the recycling and upcycling of plastic materials. It acknowledges the challenges and future perspectives in the field, particularly regarding the scalability of SSM techniques for industrial applications and their role in advancing a circular economy in the polymer industry.

Keywords

Solid state modification; thermoplastic polymers; recycling; upcycling

Subject

Chemistry and Materials Science, Chemical Engineering

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