Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Extensive Reuse of Waste Glass in Geopolymer-Like Materials

Version 1 : Received: 5 December 2023 / Approved: 6 December 2023 / Online: 6 December 2023 (03:19:49 CET)

How to cite: Ramteke, D.D.; Hujova, M.; Kraxner, J.; Galusek, D.; Elsayed, H.; Colombo, P.; Bernardo, E. Extensive Reuse of Waste Glass in Geopolymer-Like Materials. Preprints 2023, 2023120298. https://doi.org/10.20944/preprints202312.0298.v1 Ramteke, D.D.; Hujova, M.; Kraxner, J.; Galusek, D.; Elsayed, H.; Colombo, P.; Bernardo, E. Extensive Reuse of Waste Glass in Geopolymer-Like Materials. Preprints 2023, 2023120298. https://doi.org/10.20944/preprints202312.0298.v1

Abstract

The recycling of common soda-lime glass (SLG) is far from being complete, since the material may contain small polymeric, metallic and ceramic contaminations. This has a negative impact on the quality of new glass articles prepared via re-melting. Alternatively, the full reuse of contaminated cullets could be achieved by low-temperature consolidation into geopolymer-like materials. SLG powders, used either as received or pre-washed in acid solution, were added to a sodium aluminate solution at the room temperature for 3 h, under low-speed mechanical stirring. Microporous semi-crystalline monoliths were formed by the casting of suspensions in plastic molds and cured at 75°C overnight. The monoliths featured hydrosodalite as the main crystalline phase for as received SLG and LTA zeolite in the case of pre-washed SLG. The mechanical properties compared well with those of cementitious materials. Moreover, by addition of coarse glass particles as fillers, the methodology successfully yielded Venetian terrazzo-like samples, which could lead to significant material and energy savings in their manufacture. The proposed approach could also be extended to other difficult-to-reuse glass formulations and provide attractive and versatile up-cycled materials.

Keywords

alkali activation; geopolymers; glass waste; recycling

Subject

Engineering, Architecture, Building and Construction

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