Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

The Overall-Efficiency Improvement of Flexible CIGSe Solar Cells by Two-Segment Process

Version 1 : Received: 23 November 2023 / Approved: 27 November 2023 / Online: 27 November 2023 (11:51:53 CET)

How to cite: Li, T.; Ho, J.; Yu, D.; Chang, J.; Ho, J. The Overall-Efficiency Improvement of Flexible CIGSe Solar Cells by Two-Segment Process. Preprints 2023, 2023111694. https://doi.org/10.20944/preprints202311.1694.v1 Li, T.; Ho, J.; Yu, D.; Chang, J.; Ho, J. The Overall-Efficiency Improvement of Flexible CIGSe Solar Cells by Two-Segment Process. Preprints 2023, 2023111694. https://doi.org/10.20944/preprints202311.1694.v1

Abstract

In this paper, the overall performance of Cu-(In,Ga)-Se2 (CIGSe) solar cells was improved in the ultraviolet (UV)–visible wavelength region by two-segment process. In which, adjusting DC sputtering powers (20–40 W) for absorbers (segment I), and metal-alloy compositions (CdS, ZnO/CdS, ZnMgO/CdS and ZnMgO) for buffers (segment II) were explored and characterized. Upon choosing the optimal-30-W CIGSe-absorber (with 0.95-CGI ratio) sputtered by the segment-I process, the Cu-rich film can distinctly boost grain growth, thus reducing the trap state density. After segment-II process as the toxic-CdS alternative, the optimal Zn0.9Mg0.1O-alloy buffer can reach the best conversion efficiency (η = 8.70%) was attained for the environmental protection. Meanwhile, and the overall internal/external quantum efficiencies (IQE/EQE) were improved by 13.15%, respectively for the 2.48–3.62-eV bandgap (short wavelength) range. The developed photovoltaic (PV) module (with 9 optimum-CIGSe cells) exhibits acceptable stability with a variance within ±5% over the 60-day experiment. This discovery in PV-device research contributes to a new scientific understanding of renewable energy. Furthermore, this study undeniably enhances the progress of practical applications for PV-modules in alignment with sustainable development goals. It also actively supports the development of eco-friendly communities.

Keywords

Cu-(In,Ga)-Se2 (CIGSe) solar cells; Two-segment process; Metal-alloy compositions; Internal/External quantum efficiencies (IQE/EQE); Sustainable development goal; Eco-friendly community

Subject

Engineering, Electrical and Electronic Engineering

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