Krzemnicki, M.S.; Lefèvre, P.; Zhou, W.; Braun, J.; Spiekermann, G. Dehydration of Diaspore and Goethite during Low-Temperature Heating as Criterion to Separate Unheated from Heated Rubies and Sapphires. Minerals2023, 13, 1557.
Krzemnicki, M.S.; Lefèvre, P.; Zhou, W.; Braun, J.; Spiekermann, G. Dehydration of Diaspore and Goethite during Low-Temperature Heating as Criterion to Separate Unheated from Heated Rubies and Sapphires. Minerals 2023, 13, 1557.
Krzemnicki, M.S.; Lefèvre, P.; Zhou, W.; Braun, J.; Spiekermann, G. Dehydration of Diaspore and Goethite during Low-Temperature Heating as Criterion to Separate Unheated from Heated Rubies and Sapphires. Minerals2023, 13, 1557.
Krzemnicki, M.S.; Lefèvre, P.; Zhou, W.; Braun, J.; Spiekermann, G. Dehydration of Diaspore and Goethite during Low-Temperature Heating as Criterion to Separate Unheated from Heated Rubies and Sapphires. Minerals 2023, 13, 1557.
Abstract
A Gem-quality rubies and sapphires are often commercially heat treated at about 800°C or higher temperatures to enhance their colour and clarity, and hence quality. For this study, selected corundum samples containing diaspore- and goethite inclusions were heated step-by-step to a maximum of 1000 °C with the aim to monitor the dehydration and phase transformation of these oxyhydroxides to corundum and hematite during heating. Based on our experiments and in agreement with literature, the dehydration of diaspore in corundum occurs between 525 to 550 °C, whereas goethite transforms to hematite already between 300 and 325 °C. As both, diaspore and goethite are common inclusions in rubies, sapphires, and other corundum varieties, these dehydration reactions and phase transformations can be considered important criteria to separate unheated stones from heated ones, specifically in cases in which other methods (e.g. microscopy, FTIR) are unsuccessful.
Environmental and Earth Sciences, Geochemistry and Petrology
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