Preprint Review Version 1 Preserved in Portico This version is not peer-reviewed

Acetic Acid Production From Lignocellulosic Biomass Pyrolysis and Recovery via Membrane Processes

Version 1 : Received: 1 September 2023 / Approved: 4 September 2023 / Online: 6 September 2023 (14:17:42 CEST)

How to cite: Bennani, G.; Brassard, P.; Ndao, A.; Konan, D.; Leroux, É.; Godbout, S.; Adjallé, K. Acetic Acid Production From Lignocellulosic Biomass Pyrolysis and Recovery via Membrane Processes. Preprints 2023, 2023090238. https://doi.org/10.20944/preprints202309.0238.v1 Bennani, G.; Brassard, P.; Ndao, A.; Konan, D.; Leroux, É.; Godbout, S.; Adjallé, K. Acetic Acid Production From Lignocellulosic Biomass Pyrolysis and Recovery via Membrane Processes. Preprints 2023, 2023090238. https://doi.org/10.20944/preprints202309.0238.v1

Abstract

Pyrolysis is a thermochemical conversion process designed for biomass decomposition in an oxygen-free environment. It typically operates within a temperature window of 200 to 800°C and generates various byproducts, including gases, liquid fractions (both aqueous and organic) such as bio-oil, and solids like char. Bio-oil is a significant product of pyrolysis. It is characterised by a complex blend of organic compounds. The acidic nature of bio-oil primarily originates from volatile acids, such as acetic acid. The recovery of acetic acid from bio-oil facilitates the use of the extracted substance as a precious resource, hence enhancing its significance in the framework of a circular bioeconomy. Acetic acid finds widespread application in manufacturing commercially important chemicals like vinyl acetate monomers and formulating phytosanitary products due to its inherent herbicidal and antifungal properties. However, to be used, acetic acid has to be separate from the raw bio-oil. Separation methodologies, including nanofiltration and reverse osmosis, demonstrate potential in recovering acidic constituents from bio-oil due to their high selectivity and effective system management. This article offers a concise review about acetic production from lignocellulosic biomass from pyrolysis and its recovery through various membrane separation processes.

Keywords

Lignocellulosic biomass; pyrolysis; pyrolytic oil; acetic acid; nanofiltration; reverse osmosis

Subject

Chemistry and Materials Science, Materials Science and Technology

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