Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Wettability Alterations of Sui Main Limestone Carbonate Rocks Using Methylene Blue and Alumina Based Nanofluids: Implications for EOR

Version 1 : Received: 6 July 2023 / Approved: 7 July 2023 / Online: 10 July 2023 (05:07:18 CEST)

A peer-reviewed article of this Preprint also exists.

Shar, A.M.; Qureshi, M.F.; Bhutto, D.K.; Memon, F.H. Wettability Alteration of Limestone Carbonate Cores Using Methylene Blue and Alumina-Based Nanofluid: Implications for EOR. Appl. Sci. 2023, 13, 8474. Shar, A.M.; Qureshi, M.F.; Bhutto, D.K.; Memon, F.H. Wettability Alteration of Limestone Carbonate Cores Using Methylene Blue and Alumina-Based Nanofluid: Implications for EOR. Appl. Sci. 2023, 13, 8474.

Abstract

The wettability of the oil-brine-rock systems is very challenging mainly for the carbonate reservoirs and it plays a significant role to enhance the oil recovery (EOR). Carbonate rocks are mad-up of complex lithology, hence these requires careful treatments in controlling their wetting behavior for enhanced oil recovery. Therefore, it is extremely important to modify their wettability from an oil-wet rock behavior to a water-wet so that the residual oil can be produced efficiently. Thus, the present study has examined the effectiveness of alumina nanofluid as well as a new chemical methyl blue to alter the wettability. The methyl blue is released on massive scale from various industries i.e. pharma, textile and food industry which is a key environmental concern which contaminates the water table. Hence the study, explores the effects of MB and alumina nanofluid on the wettability. The effect of nanofluids formulated via dispersing the alumina nanoparticles in aqueous solutions at various concentration (0. 0.05, 0.3, 0.50, 0.75 and 1.0 wt. %) were tested for wettability modification under different physio-thermal conditions. Subsequently, the wettability change was examined for the samples treated with different concentrations of MB (10, 15, 30, 50 and 100 mg/L) for 7-days at two different temperatures of (25 and 50 0C). The results showed that hydrophobicity of the SML carbonate rock has significantly reversed while treating with alumina nanofluids and MB. Thus, the wettability modification/reversal via treatment of MB and alumina nanofluid can be an effective mechanism to hydrogen injection and for EOR processes.

Keywords

Wettability; carbonate rock; Sui main limestone; Methylene blue; enhanced oil recovery

Subject

Engineering, Energy and Fuel Technology

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