Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Synergistic Effects of LSPR, SPP, and Waveguide Plasmonic Resonance on the Same Material: A Promising Hypothesis to Enhanced Organic Solar Cells Efficiency

Version 1 : Received: 27 June 2023 / Approved: 28 June 2023 / Online: 28 June 2023 (12:21:12 CEST)

A peer-reviewed article of this Preprint also exists.

Ibrahim Zamkoye, I.; Lucas, B.; Vedraine, S. Synergistic Effects of Localized Surface Plasmon Resonance, Surface Plasmon Polariton, and Waveguide Plasmonic Resonance on the Same Material: A Promising Hypothesis to Enhance Organic Solar Cell Efficiency. Nanomaterials 2023, 13, 2209. Ibrahim Zamkoye, I.; Lucas, B.; Vedraine, S. Synergistic Effects of Localized Surface Plasmon Resonance, Surface Plasmon Polariton, and Waveguide Plasmonic Resonance on the Same Material: A Promising Hypothesis to Enhance Organic Solar Cell Efficiency. Nanomaterials 2023, 13, 2209.

Abstract

In this work we explore the utilization of plasmonic resonance (PR) in silver nanowires to enhance the performance of organic solar cells. Plasmonic resonance is a phenomenon in which nanoscale conductive materials exhibit oscillation of conduction electrons, resulting in the creation of an electric field. Enhancing light absorption is crucial for improving organic solar cell efficiency and incorporating metallic nanostructures to induce surface plasmon resonance (SPR) shows promise in achieving this goal. We discuss the two key mechanisms of plasmonic effects: far-field scattering and near-field resonance modes. Far-field scattering extends the optical path of incident light, while near-field plasmonic effects involve localized surface plasmon resonance (LSPR) and plasmonic cavity modes, enhancing absorption by strengthening electric fields near the nanostructures. Silver nanowires are the focus of this study, and finite-difference time-domain (FDTD) simulation software is used to investigate their plasmonic resonance behavior in a ZnO/Silver nanowires/ZnO (ZAZ) electrode structure. The simulations reveal the dominance of LSPR in this configuration, with intense electric fields inside the nanowire and propagation into the surrounding medium, offering opportunities for enhanced light absorption in the organic solar cell's active layer.

Keywords

plasmonic resonance; LSPR; SPP; silver nanowires; organic solar cells; finite-difference time domain simulation; electrode.

Subject

Physical Sciences, Optics and Photonics

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