Preprint Communication Version 1 Preserved in Portico This version is not peer-reviewed

Behavior of C70 Fullerene in a Binary Mixture of Xylene and Tetrahydrofuran

Version 1 : Received: 20 June 2023 / Approved: 20 June 2023 / Online: 20 June 2023 (09:35:19 CEST)

A peer-reviewed article of this Preprint also exists.

Makhmanov, U.K.; Esanov, S.A.; Sidigaliyev, D.T.; Musurmonov, K.N.; Aslonov, B.A.; Chuliev, T.A. Behavior of C70 Fullerene in a Binary Mixture of Xylene and Tetrahydrofuran. Liquids 2023, 3, 385-392. Makhmanov, U.K.; Esanov, S.A.; Sidigaliyev, D.T.; Musurmonov, K.N.; Aslonov, B.A.; Chuliev, T.A. Behavior of C70 Fullerene in a Binary Mixture of Xylene and Tetrahydrofuran. Liquids 2023, 3, 385-392.

Abstract

The self-organization properties of C70 fullerene molecules in a xylene/tetrahydrofuran binary mixture were studied for the first time by optical absorption, refractometry, and dynamic light scattering. A correlation has been established between the change in the refractive index of the C70/xylene/tetrahydrofuran solution and the degree of self-organization of C70 molecules in the medium at various concentrations and storage periods of the solution. It is shown that the features of the optical absorption spectrum of C70/xylene/tetrahydrofuran at a fixed low concentration of the fullerene are sensitive to its storage time. It was determined that the beginning time of the formation of C70 nanoclusters and their final size depend on the concentration of fullerene and the time of keeping the solution. The observed nature of the C70 fullerene solution in a binary mixture may help to elucidate the mechanism of self-organization in the future.

Keywords

C70 fullerene; xylene/tetrahydrofuran; self-organization; refractive index; DLS; UV-Vis absorption; nanocluster

Subject

Physical Sciences, Optics and Photonics

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