Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Composite Membrane Based on Graphene Oxide and Carboxymethylcellulose from Local Kazakh Raw Materials for Possible Applications in Electronic Devices

Version 1 : Received: 16 May 2023 / Approved: 16 May 2023 / Online: 16 May 2023 (07:55:44 CEST)

How to cite: Kuanyshbekov, T.; Sagdollin, Z.; Zhasasynov, E.; Akatan, K.; Kurbanova, B.; Guseinov, N.; Tolepov, Z.; Kantay, N.; Beisebekov, M. Composite Membrane Based on Graphene Oxide and Carboxymethylcellulose from Local Kazakh Raw Materials for Possible Applications in Electronic Devices. Preprints 2023, 2023051122. https://doi.org/10.20944/preprints202305.1122.v1 Kuanyshbekov, T.; Sagdollin, Z.; Zhasasynov, E.; Akatan, K.; Kurbanova, B.; Guseinov, N.; Tolepov, Z.; Kantay, N.; Beisebekov, M. Composite Membrane Based on Graphene Oxide and Carboxymethylcellulose from Local Kazakh Raw Materials for Possible Applications in Electronic Devices. Preprints 2023, 2023051122. https://doi.org/10.20944/preprints202305.1122.v1

Abstract

In nowadays, the synthesis of new composite nanomaterials based on graphene oxide (GO) modified with cellulose and its derivatives, as well as nanocellulose, is an important direction and contributes to solve many problems in various fields such as: nanotechnology, information technology, medicine, high-dielectric materials and nanoelectronics. In this work, for the first time, for the production of GO and its membrane with carboxymethylcellulose (CMC), local Kazakhstan “Ognevsky” graphite was used as the initial raw material. In this regard, the preparation of nanocomposites of GO modified with cellulose derivatives, including CMC, attracts great interest from scientists and expands its field of practical application due to the amazing changes of physicochemical properties. In the work, the GO obtained by the Hummers method was modified by CMC, with following study of its physicochemical, structural and electrical characteristics. The GO/CMC membrane was synthesized by mixing 1% GO with crushed solid mass of CMC (0.03 g; 0.06 g; 0.15 g) and then was processed by ultrasound. The surface morphology of the GO/CMC membrane were studied using Scanning electron microscopy (SEM). It has been established that with an increasing in the mass of CMC (0.03 g; 0.06 g; 0.15 g), polymerization of CMC occurs on the surface of GO nanosheets. Cross-sectional micrographs of GO/CMC show the formation of sandwich-like layered structures.

Keywords

graphene oxide; carboxymethylcellulose; membrane; nanocomposite; resistivity

Subject

Chemistry and Materials Science, Materials Science and Technology

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