Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer using Ca(EDTA) Complex Decomposition

Version 1 : Received: 2 May 2023 / Approved: 3 May 2023 / Online: 3 May 2023 (06:48:28 CEST)

A peer-reviewed article of this Preprint also exists.

Yurova, V.Y.; Zyrianova, P.I.; Nesterov, P.V.; Goncharov, V.V.; Skorb, E.V.; Ulasevich, S.A. Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition. Catalysts 2023, 13, 993. Yurova, V.Y.; Zyrianova, P.I.; Nesterov, P.V.; Goncharov, V.V.; Skorb, E.V.; Ulasevich, S.A. Photodeposition of Hydroxyapatite into a Titanium Dioxide Nanotubular Layer Using Ca(EDTA) Complex Decomposition. Catalysts 2023, 13, 993.

Abstract

A new photocatalytic hydroxyapatite (HA) synthesis method has been developed. This method is based on the unique ability of the TiO2 photocatalyst to decompose the Ca(EDTA) complex under UV illumination. As a result, released Ca2+ ions react with PO43- ions forming the HA particles. The photocatalytic formation of hydroxyapatite is found to have a fractional order, which may indicate the complex reaction mechanism and the presence of several limiting stages. The TNT-HA samples were studied by XRD, FTIR, SEM, GDOES, and biocompatibility study. High biocompatibility of the surfaces is proven by pre-osteoblast cell growth.

Keywords

Photodeposition; hydroxyapatite; titania nanotubes; Ca(EDTA) complex decomposition

Subject

Chemistry and Materials Science, Other

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