Rahman, M.; Maeda, T.; Osada, T.; Ozaki, S. Method of Determining Kinetic Parameters of Strength Recovery in Self-Healing Ceramic Composites. Materials2023, 16, 4079.
Rahman, M.; Maeda, T.; Osada, T.; Ozaki, S. Method of Determining Kinetic Parameters of Strength Recovery in Self-Healing Ceramic Composites. Materials 2023, 16, 4079.
Rahman, M.; Maeda, T.; Osada, T.; Ozaki, S. Method of Determining Kinetic Parameters of Strength Recovery in Self-Healing Ceramic Composites. Materials2023, 16, 4079.
Rahman, M.; Maeda, T.; Osada, T.; Ozaki, S. Method of Determining Kinetic Parameters of Strength Recovery in Self-Healing Ceramic Composites. Materials 2023, 16, 4079.
Abstract
Self-healing ceramic composites are promising smart materials for high-temperature applications. To better understand their behaviors under service conditions, numerous studies have been performed both experimentally and numerically, and kinetics parameters such as activation energy and frequency factor are reported to be indispensable for investigating healing phenomena. Here, we propose a method for determining the kinetic parameters of self-healing ceramic composites based on the oxidation kinetics model of strength recovery. These parameters are determined by an optimization method using experimental strength recovery data under various healing temperatures and times and microstructural features on the fractured surfaces. Alumina and mullite matrix-based self-healing ceramic composites, such as Al2O3/SiC, Al2O3/TiC, Al2O3/Ti2AlC (MAX phase), and mullite/SiC, were selected as target materials. The theoretical strength recovery behaviors of the cracked specimens obtained from the determined kinetic parameters were compared with the experimental results. The determined parameters are within the previously reported range, and the predicted strength recovery behaviors are reasonably agreed with the experimental values. The proposed method can also be applied to other self-healing ceramics with matrices reinforced with different healing agents to evaluate oxidation rate, crack healing rate, and theoretical strength recovery behaviors for designing self-healing materials used in high temperature applications. Furthermore, the healing ability of composites can be fairly discussed regardless of the type of strength recovery test.
Keywords
self-healing ceramics; oxidation kinetics; activation energy; frequency factor; strength recovery
Subject
Engineering, Mechanical Engineering
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
