Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Microstructural Study of CrNiCoFeMn High Entropy Alloy Obtained by Selective Laser Melting

Version 1 : Received: 20 June 2022 / Approved: 21 June 2022 / Online: 21 June 2022 (10:52:27 CEST)

A peer-reviewed article of this Preprint also exists.

Campari, E.G.; Casagrande, A. Microstructural Study of CrNiCoFeMn High Entropy Alloy Obtained by Selective Laser Melting. Materials 2022, 15, 5544. Campari, E.G.; Casagrande, A. Microstructural Study of CrNiCoFeMn High Entropy Alloy Obtained by Selective Laser Melting. Materials 2022, 15, 5544.

DOI: 10.3390/ma15165544

Abstract

The high entropy alloy (HEA) of equiatomic composition CrNiFeCoMn and with FCC crystal structure was additively manufactured with a selective laser melting (SLM) process starting from mechanically alloyed powders. The as produced alloy shows finenitride and  phase pre-cipitates, which are Cr-rich and stable up to about 900 K. The precipitates increase in number and dimensions after long-period annealing at 900-1300 K, with a change in the HEA mechanical properties. Higher aging temperatures in furnace, above 1300 K, turn the alloy in a single FCC structure, with disappearance of the nitrate and  phase precipitates inside the grains and at the grain boundaries, but with still a presence of a finer Cr-rich nitride precipitation phase. These re-sults suggest that the as-produced HEA is a supersatured solid solution at low and intermediate temperature with nitrides and  nanostructures.

Keywords

high entropy alloys; selective laser melting; microstructure; mechanical properties; strengthening mechanism

Subject

MATERIALS SCIENCE, Metallurgy

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