Version 1
: Received: 28 June 2021 / Approved: 30 June 2021 / Online: 30 June 2021 (09:40:52 CEST)
How to cite:
Sun, Z.; Xu, H.; Yuan, F.; Zhou, S.; Zhou, H.; Han, W. Effect of B Incorporation on the SiOC Precursor Fabrication and High-temperature Oxidation Behavior of SiBOC Ceramics. Preprints2021, 2021060723
Sun, Z.; Xu, H.; Yuan, F.; Zhou, S.; Zhou, H.; Han, W. Effect of B Incorporation on the SiOC Precursor Fabrication and High-temperature Oxidation Behavior of SiBOC Ceramics. Preprints 2021, 2021060723
Sun, Z.; Xu, H.; Yuan, F.; Zhou, S.; Zhou, H.; Han, W. Effect of B Incorporation on the SiOC Precursor Fabrication and High-temperature Oxidation Behavior of SiBOC Ceramics. Preprints2021, 2021060723
APA Style
Sun, Z., Xu, H., Yuan, F., Zhou, S., Zhou, H., & Han, W. (2021). Effect of B Incorporation on the SiOC Precursor Fabrication and High-temperature Oxidation Behavior of SiBOC Ceramics. Preprints. https://doi.org/
Chicago/Turabian Style
Sun, Z., Haiou Zhou and Wenbo Han. 2021 "Effect of B Incorporation on the SiOC Precursor Fabrication and High-temperature Oxidation Behavior of SiBOC Ceramics" Preprints. https://doi.org/
Abstract
The SiBOC precursor ceramics were fabricated by polymer-derived method SiBOC precursors with different B/Si molar ratios were synthesized by controlling monomer content. The effects of different process conditions on SiBOC ceramics and the oxidation resistance of SiBOC ceramics at a high temperature (1400 ℃) were studied. The SiBOC precursor’s bonds of Si-O-C, Si-O-Si, and Si-O-B were detected by FTIR. The precursor is converted to a rigid ceramic material that has an 85.3 wt % ceramic yield of SiBOC ceramics with B/Si=0.4 by TG-DSC. The results of SEM analysis show that the SiBOC ceramics surface bulges and folds increase with the increase of boric acid content. With the increase of pyrolysis temperature and pyrolysis time, the size and number of pores on the surface of SiBOC ceramics also increase. Static oxidation tests show that SiBOC ceramics with B/Si=0.4 have better oxidation resistance under other conditions being the same.
Chemistry and Materials Science, Analytical Chemistry
Copyright:
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
