Uylings, P.; Raassen, T. Orthogonal Operators: Applications, Origin and Outlook. Atoms2019, 7, 102.
Uylings, P.; Raassen, T. Orthogonal Operators: Applications, Origin and Outlook. Atoms 2019, 7, 102.
Orthogonal operators can successfully be used to calculate eigenvalues and eigenvector compositions in complex spectra. Orthogonality ensures least correlation between the operators and thereby more stability in the fit, even for small interactions. The resulting eigenvectors are used to transform the pure transition matrix into realistic intermediate coupling transition probabilities. Calculated transition probabilities for close lying levels illustrate the power of the complete orthogonal operator approach.
atomic lifetime and oscillator strength determination; theoretical modeling and computational approaches; atomic databases and related topics
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