Preprint Review Version 1 This version is not peer-reviewed

General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis

Version 1 : Received: 12 September 2018 / Approved: 13 September 2018 / Online: 13 September 2018 (02:17:55 CEST)

A peer-reviewed article of this Preprint also exists.

Valange, S.; Védrine, J.C. General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis. Catalysts 2018, 8, 483. Valange, S.; Védrine, J.C. General and Prospective Views on Oxidation Reactions in Heterogeneous Catalysis. Catalysts 2018, 8, 483.

Journal reference: Catalysts 2018, 8, 483
DOI: 10.3390/catal8100483

Abstract

In this short review paper we have assembled the main characteristics of partial oxidation reactions (oxidative dehydrogenation and selective oxidation to olefins or oxygenates, as aldehydes and carboxylic acids and nitriles), as well as total oxidation, particularly for depollution, environmental issues and wastewater treatments. Both gas-solid and liquid-solid media have been considered with recent and representative examples within these fields. We have also discussed about their potential and prospective industrial applications. Particular attention has been brought to new raw materials stemming from biomass and to liquid-solid catalysts cases. This review paper also summarizes the progresses made in the use of unconventional activation methods for performing oxidation reactions, highlighting the synergy of these technologies with heterogeneous catalysis. Focus has been centered on usual catalysts activation methods but also on less usual ones, such as the use of ultrasounds, microwaves, grinding (mechanochemistry) and photo-activated processes, as well as their combined use.

Subject Areas

heterogeneous catalytic oxidation, gas-solid, liquid-solid, partial and total oxidation, biomass based raw materials, activation methods

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