Preprint Review Version 1 This version is not peer-reviewed

Chirality Induction in Bioorganometallic Conjugates

Version 1 : Received: 12 September 2018 / Approved: 12 September 2018 / Online: 12 September 2018 (11:25:32 CEST)

A peer-reviewed article of this Preprint also exists.

Moriuchi, T.; Ohmura, S.D.; Moriuchi-Kawakami, T. Chirality Induction in Bioorganometallic Conjugates. Inorganics 2018, 6, 111. Moriuchi, T.; Ohmura, S.D.; Moriuchi-Kawakami, T. Chirality Induction in Bioorganometallic Conjugates. Inorganics 2018, 6, 111.

Journal reference: Inorganics 2018, 6, 111
DOI: 10.3390/inorganics6040111

Abstract

Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry. The introduction of biomolecules, which have hydrogen bonding sites and chiral centers, into organometallic compounds is considered to be a promising strategy to construct chirality-organized bioorganometallic conjugates. This feature paper sketches an outline of induction of helical chirality into bioorganometallic conjugates. Topics covered include control of the helical chirality of 1,n’-disubstituted ferrocene moieties in ferrocene-dipeptide conjugates and the chirality induction of the Au(I)–Au(I) axis in the dinuclear organogold(I)-uracil conjugates.

Subject Areas

chirality induction; helical chirality; bioorganometallic conjugate; dipeptide; nucleobase; ferrocene; organogold(I); self-assembly; hydrogen bond; Au(I)-Au(I) interaction

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