Preprint Article Version 1 Preserved in Portico This version is not peer-reviewed

Synthesis of Poly (Methyl Methacrylate-Co-Butyl Acrylate)/Perfluorosilyl Methacrylate Core–Shell Nanoparticles: Novel Approach for Optimization of Coating Process

Version 1 : Received: 8 May 2018 / Approved: 8 May 2018 / Online: 8 May 2018 (15:15:15 CEST)

How to cite: Kook, J.; Kim, Y.; Hwang, K.; Kim, J.H.; Lee, J. Synthesis of Poly (Methyl Methacrylate-Co-Butyl Acrylate)/Perfluorosilyl Methacrylate Core–Shell Nanoparticles: Novel Approach for Optimization of Coating Process. Preprints 2018, 2018050131. https://doi.org/10.20944/preprints201805.0131.v1 Kook, J.; Kim, Y.; Hwang, K.; Kim, J.H.; Lee, J. Synthesis of Poly (Methyl Methacrylate-Co-Butyl Acrylate)/Perfluorosilyl Methacrylate Core–Shell Nanoparticles: Novel Approach for Optimization of Coating Process. Preprints 2018, 2018050131. https://doi.org/10.20944/preprints201805.0131.v1

Abstract

In this study, the coating order of two monomers in the shell polymerization process of core–shell nanoparticles was altered to facilitate easy coating and optimize the properties of the coated surface to simplify the additional coating formulation process. To obtain a glass transition temperature suitable for coating, a core was synthesized by the copolymerization of an acryl monomer. A perfluoro monomer and silane monomer were additionally added to synthesize nanoparticles exhibiting both water–oil repellency and anchoring properties. In order to realize various surface properties, the nanoparticles underwent surface modification and cellulose fiber was introduced. Through the various data described in this text, the surface properties improved with the order of introduction of the two monomers.

Keywords

Core-shell nanoparticles; Optimization; Surface properties; Perfluorosilyl methacrylate

Subject

Chemistry and Materials Science, Surfaces, Coatings and Films

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